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中国农学通报 ›› 2014, Vol. 30 ›› Issue (12): 171-175.doi: 10.11924/j.issn.1000-6850.2013-2259

• 农学 农业基础科学 • 上一篇    下一篇

氧化亚铜复配杀菌剂的制备及其抑菌性能研究

于专妮 王强   

  • 收稿日期:2013-08-26 修回日期:2013-09-24 出版日期:2014-04-25 发布日期:2014-04-25
  • 基金资助:
    山东省高等学校青年骨干教师国内访问学者项目;青岛农业大学高才次人才启动基金“复合型波尔多液的制备、性能及其应用研究”(631203);青岛市科技计划基础研究项目“包覆氧化亚铜的温度敏感型微胶囊的制备、性能及其农业应用研究”(13-1-4-233-jch)。

Preparation and Antibacterial Activity of Cu2O and its Mixtures

  • Received:2013-08-26 Revised:2013-09-24 Online:2014-04-25 Published:2014-04-25

摘要: 为了进一步提升无机铜系杀菌剂的抑菌性能,采用果糖一锅还原法制备出氧化亚铜,并对所得样品进行XRD分析和SEM表征。并通过抑菌圈实验考察所得产品及其与氧化锌和六次甲基四胺分别复配后对农业常见病菌的抑制效果。结果发现,当氧化亚铜的量为0.5 mg/mL时,对柑橘炭疽菌、苹果腐烂菌、黄瓜枯萎菌和小麦全蚀菌的抑制效果明显,抑制率超过90%;当氧化锌或六次甲基四胺与氧化亚铜的质量比约为1:2时,复配杀菌剂对辣椒炭疽病菌或葡萄白腐病菌的抑制作用明显增强,复配体系实现了有效组分协同杀菌的目的。

关键词: 对策, 对策

Abstract: In order to improving the antibacterial activity property of inorganic copper-based fungicides, Cu2O nanocrystal was prepared via a facile one-pot synthesis by the reduction of fructose in the paper. The sample was characterized by XRD and SEM. In addition, their antibacterial activity of Cu2O nanocrystal and its mixtures containing ZnO and methenamine were also investigated by inhibition zone method. The result suggested cuprous oxide presented active inhibition to Colletotrichum glecosporioides, Valsa mali, Cucumber wilt and Gaeumannomyces graminis var tritici. The inhibition rate of cuprous oxide was more than 90% once its concentration was 0.5 mg/mL. At the same time, the better antibacterial activity to Colletotrichum capsici and Coniothyrium diplodiella, was reached when the mass of ratio of ZnO or methenamine and Cu2O was up to 1:2 respectively. The synergism was disclosed in our experiments.