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中国农学通报 ›› 2010, Vol. 26 ›› Issue (24): 343-347.

• 资源 环境 生态 土壤 气象 • 上一篇    下一篇

超临界CO2为快挥发溶剂丙烯酸清漆喷涂研究Ⅱ.——丙烯酸清漆喷涂工艺条件的选择

李喜载 李娟 黄丽红   

  • 收稿日期:2010-11-16 修回日期:2010-11-18 出版日期:2010-12-20 发布日期:2010-12-20
  • 基金资助:

    福建省自然科学基金项目;福建省科技三项经费资助项目

Elementary study on spray coating of acrylic acid using supercritical CO2 as highly volatile solventⅡ. Selection of acrylic acid coating spraying techincs condition

  • Received:2010-11-16 Revised:2010-11-18 Online:2010-12-20 Published:2010-12-20

摘要:

摘要:测定了超临界CO2-丙烯酸树脂-二甲苯拟三元体系相图,考察了喷嘴结构对含超临界CO2-丙烯酸涂料雾化效果的影响,用L9(34)正交表考察了涂料中超临界CO2含量、压力、温度对喷化粒子直径及喷化粒子流锥角的影响,结果表明:当温度低于90℃、压力大于8MPa、CO2含量不超过35%时SC-CO2—丙烯酸树脂—二甲苯三元体系处在稳定单相区。用孔径为0.4mm,长度为<1mm的电火花钻孔喷嘴进行喷涂能够得到良好的喷涂效果,所得雾化粒子直径为80μm。温度越高、压力越大、CO2含量越大雾化粒子越小,喷雾锥角越大,雾化效果越好。在优化组合条件(20MPa、80℃、 CO2含量为35%)下喷涂,所得涂膜试样主要性能达到国家标准.

关键词: 蔬菜 农药残留 特点 控制, 蔬菜 农药残留 特点 控制

Abstract:

The pseudo-ternary phase diagram of supercritical CO2- acrylic acid resin- dimethylbenzene was determined. The influence of nozzle’s structure on the effect of acrylic acid varnish spraying atomization including supercritical CO2 was investigated. The influences of temperature, pressure and CO2 content on the magnitude of atomization particles and spraying angle were investigated by using L9(34) orthogonal experiments.The result indicated that when spraying operation satisfied these conditions(the temperature is less than 90℃,the pressure is larger than 8Mpa,and the CO2 content is not more than 35%,the above pseudo-ternary system is in stable monophase field.The favorable spraying effect is gained using nozzle with diameter of 0.4mm and length less than 1mm, and the diameter of atomization particles obtained is 80μm. The higher index of temperature,pressure and CO2 content, the smaller magnitude of atomization particles, the larger spraying angle and the better effect of atomization. The optimization condition was 20Mpa, 80℃, CO2 35%, coating film samples attained achieved the national standard under the optimization condition (20Mpa, 80℃, CO2 35%).

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