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中国农学通报 ›› 2020, Vol. 36 ›› Issue (1): 135-138.doi: 10.11924/j.issn.1000-6850.casb18090014

所属专题: 植物保护

• 植物保护·农药 • 上一篇    下一篇

植物源活性成分对有机磷农药的降解效果研究

张同心1, 李慧冬2,3(), 张洪启4   

  1. 1 山东礽健生物科技有限公司,济南 250200;
    2 山东省农业科学院农业质量标准与检测技术研究所,农业部农产品质量安全风险评估实验室(济南),济南 250100;
    4 莘县农业局土肥站,山东莘县 252400
  • 收稿日期:2018-09-04 修回日期:2018-10-10 出版日期:2020-01-05 发布日期:2020-01-07
  • 通讯作者: 李慧冬
  • 作者简介:张同心,男,1977年出生,山东济南人,高级工程师,博士,研究方向:土壤修复。通信地址:250200 山东省济南市章丘青年创业创新园 山东礽健生物科技有限公司,E-mail:daxin1996@163.com。
  • 基金资助:
    山东省自然科学基金“混合农药联合毒性效应与膳食摄入风险评估”(ZR2016YL027);山东省农业科学院科技创新工程“农业检验检测公共服务平台”(CXGC2017A03)

Botanical Active Components Degrades Organophosphorus Pesticides

Zhang Tongxin1, Li Huidong2,3(), Zhang Hongqi4   

  1. 1 Shandong Rengjian Biotechnical Co., Ltd, Jinan 250200;
    2 Quality Standard Institute of Shandong Academy of Agricultural Sciences, Agricultural Products Quality and Safety Risk Assessment Laboratory of Ministry of Agriculture, Jinan 250100;
    4 Soil and Fertilizer Station of Shenxian Agricultural Bureau, Shenxian Shandong 252400
  • Received:2018-09-04 Revised:2018-10-10 Online:2020-01-05 Published:2020-01-07
  • Contact: Li Huidong

摘要:

为探索有机磷农药降解的新途径和方法,以大黄、海桐皮、木槿皮、五倍子按9:4:3:2质量份数混合,粉碎并以水浸泡,以GC-MS定量检测法、农残速测法,通过比较试验前后有机磷农药浓度变动,明确其对有机磷农药的降解效果。结果表明,2 min内浸提液对毒死蜱、对硫磷2种有机磷农药降解率分别达到93.6%、92.9%;浸提液17 h内对敌敌畏降解率为66.67%,11 h内对毒死蜱降解率为48.69%。本研究表明,大黄、海桐皮、木槿皮、五倍子浸提液对毒死蜱、对硫磷、敌敌畏等有机磷农药有显著降解效果。

关键词: 有机磷农药, 植物源活性成分, 农药降解, 中医农业, 土壤修复

Abstract:

To explore the new way of organophosphorus pesticides degradation, according to the weight proportion of 9:4:3:2, Rheum palmatum L., Aralia chinensis L., Hibiscus syriacus Linn., Rhus chinensis Mill. were mixed, then smashed into the powder which was soaked with water for the experiments. Using the GC-MS method and fast testing method for pesticide residues, the degradation effect of organophosphorus was clarified by comparing the concentration dynamics of the pesticides. The results showed that the degradation rates of chlorpyrifos and thiophos in 2 minutes were respectively 93.6% and 92.9%. The degradation rate of dichlorvos in 17 hours was 66.67%, and the rate of chlorpyrifos in 11 hours was 48.69%. The experiments showed that leaching solution of Rheum palmatum L., Aralia chinensis L., Hibiscus syriacus Linn., Rhus chinensis Mill. had significant degradation effect on organophosphorus pesticides, such as chlorpyrifos, thiophos and dichlorvos.

Key words: organophosphorus pesticide, botanical active components, pesticide degradation, Chinese medicine agriculture, soil remediation

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