Jiaozuo city is one of the cities with most serious air pollution at home and abroad. In the paper Jiaozuo was selected as research area. The TSP and dustfall was serially monitored in different type districts. The contents of Hg Cd and Pb were analyzed in air settlement. The results showed that import amount of Hg Cd and Pb lead on soil were Hg4.43 g/hm2.a、Cd5.70 g/hm2.a、Pb394.6 g/hm2.a; their amount was unanimous with pollution levels of air. Its order was Yanma mining area and Zhucun mining area>the suburbs and the city proper>outer suburbs and park.