改性纤维素的吸附性能及应用研究进展

doi:10.11924/j.issn.1000-6850.casb18090032

摘要/Abstract

摘要：

纤维素作为天然生物基材料来源广泛,纤维素的改性及其在吸附方面的应用一直作为研究的热点。笔者介绍了纤维素基本结构,综述了纤维素化学改性方法以及改性纤维素对水体污染物吸附能力的提高。重点从改性纤维素良好的吸附性、吸附机理以及对水体中金属离子和水体中氮磷的吸附性展开叙述。提出了改性纤维素可应用于土壤当中,以期为土壤改良、作物高产提供全面的科学解释;同时改性纤维素可与肥料相结合,提高肥料利用率减缓因施肥造成的面源污染等问题。

关键词: 纤维素, 化学改性, 水体污染物, 吸附性, 天然生物基材料

Abstract:

Cellulose is widely used as a natural bio-based material. The modification of cellulose and its application in adsorption have been the focus of research. In addition to introduce the basic structure of modified cellulose, this thesis summarizes the cellulose that modified by chemical modification and the high adsorption capacity of modified cellulose for various aquatic pollutants. We focus on the adsorption, adsorption mechanism of modified fiber and adsorption of metal ions and nitrogen and phosphorus in water. Moreover, this thesis also suggests that applying modified fiber material to soil could provide a comprehensive explanation for soil improvement and crop yield. Meanwhile, combining the modified cellulose with fertilizer improves the utilization rate of fertilizer and reduces the non-point source pollution caused by fertilization.

Key words: cellulose, chemical modification, aquatic pollutants, adsorption, natural bio-based material

中图分类号:

邢磊, 杨世琦. 改性纤维素的吸附性能及应用研究进展[J]. 中国农学通报, 2020, 36(3): 59-65.

Xing Lei, Yang Shiqi. Adsorption Properties and Application of Modified Cellulose: A Review[J]. Chinese Agricultural Science Bulletin, 2020, 36(3): 59-65.

图/表 1

参考文献 61

[1]	Lichtfouse E, Schwarzbauer J, Robert D , et al. Green Materials for Energy, Products and Depollution[J]. Environmental Chemistry for A Sustainable World, 2017,3. doi: 10.3390/ma11050820 URL pmid: 29772733
[2]	Gupta V K, Ali I . Chapter 2-Water Treatment for Inorganic Pollutants by Adsorption Technology[J]. Environmental Water, 2013,70(4):29-91.
[3]	Yeo T H C, Tan I A W, Abdullah M O . Development of adsorption air-conditioning technology using modified activated carbon—A review[J]. Renewable & Sustainable Energy Reviews, 2012,16(5):3355-3363.
[4]	Hubbe M A, Hasan S H, Ducoste J J . Cellulosic substrates for removal of pollutants from aqueous systems: a review. 1. Metals[J]. Bioresources, 2011,6(2):1-201.
[5]	Hubbe M A, Beck K R, O'Neal W G , et al. Cellulosic substrates for removal of pollutants from aqueous systems: a review. 2. Dyes.[J]. Bioresources, 2012,7(2).
[6]	Hubbe M A, Rojas O J, Fingas M , et al. Cellulosic substrates for removal of pollutants from aqueous systems: a review. 3. Spilled oil and emulsified organic liquids.[J]. Bioresources, 2013,8(2):3038-3097.
[7]	Habibi Y, Lucia L A, Rojas O J . Cellulose nanocrystals: chemistry, self-assembly, and applications[J]. Chemical Reviews, 2010,110(6):3479-3500. doi: 10.1021/cr900339w URL pmid: 20201500
[8]	张晓光 . 纤维素海绵制备及性能研究[D]. 济南:齐鲁工业大学, 2015.
[9]	Hokkanen S, Bhatnagar A, Sillanpää M . A review on modification methods to cellulose-based adsorbents to improve adsorption capacity[J]. Water Research, 2016,91:156-173. doi: 10.1016/j.watres.2016.01.008 URL pmid: 26789698
[10]	陈筠 . 纤维素纳米晶的炔基化修饰及其改性材料的研究[D]. 武汉:武汉理工大学, 2015.
[11]	A.M. Nada, Mohamed Y. Alkady, Hesham M. Fekry . Synjournal and characterization of grafted cellulose foruse in water and metal ions sorption[J]. Biological Research, 2008,3:46-59.
[12]	Kubota H, Shigehisa Y . Introduction of amidoxime groups into cellulose and its ability to adsorb metal ions[J]. Journal of Applied Polymer Science, 2010,56(2):147-151. doi: 10.1002/app.1995.070560204 URL
[13]	Chand P, Shil A K, Sharma M , et al. Improved adsorption of cadmium ions from aqueous solution using chemically modified apple pomace: Mechanism, kinetics, and thermodynamics[J]. International Biodeterioration & Biodegradation, 2014,90(4):8-16.
[14]	Guerra D J L, Goco J, Nascimento J , et al. Adsorption of divalent metals on natural and functionalized nontronite hybrid surfaces: An evidence of the chelate effect[J]. Journal of Saudi Chemical Society, 2016,20(1):S552-S565. doi: 10.1016/j.jscs.2013.03.008 URL
[15]	Fox-Beyer B S, Wüllen C V . Theoretical modelling of the adsorption of thallium and element 113 atoms on gold using two-component density functional methods with effective core potentials[J]. Chemical Physics, 2012,395(2):95-103. doi: 10.1016/j.chemphys.2011.04.029 URL
[16]	Fox S C, Li B, Xu D , et al. Regioselective Esterification and Etherification of Cellulose: A Review[J]. Biomacromolecules, 2011,12(6):1956-1972. doi: 10.1021/bm200260d URL
[17]	Zheng M Y, Wang A Q, Ji N , et al. Transition metal-tungsten bimetallic catalysts for the conversion of cellulose into ethylene glycol[J]. Chemsuschem, 2010,3(1):63-66. doi: 10.1002/cssc.200900197 URL pmid: 19998362
[18]	Saito T, Isogai A . Ion-exchange behavior of carboxylate groups in fibrous cellulose oxidized by the TEMPO-mediated system[J]. Carbohydrate Polymers, 2005,61(2):183-190. doi: 10.1016/j.carbpol.2005.04.009 URL
[19]	Zhou Y, Jin Q, Zhu T , et al. Separation of chromium (VI) from aqueous solutions by cellulose modified with D-glucose and quaternary ammonium groups[J]. Cellulose Chemistry and Technology. 2012,46(5-6):319-329.
[20]	Awang N A, Salleh W N W, Hasbullah H , et al. Graft copolymerization of acrylonitrile onto recycled newspapers cellulose pulp [C].American: American Institute of Physics Conference Series, 2017.
[21]	Ignazio Renato Bellobono, Seba Calgari, Maria Cristina Leonardi , et al. Photochemical grafting of acrylated azo dyes onto polymeric surfaces, IV. Grafting of 4-(N-ethyl-N-2-acryloxyethyl)amino-4′-nitro-azobenzene onto cellulose[J]. Macromolecular Materials & Engineering, 1981,100(1):135-146.
[22]	Desmet G, Takács E, Wojnárovits L , et al. Cellulose functionalization via high-energy irradiation-initiated grafting of glycidyl methacrylate and cyclodextrin immobilization[J]. Radiation Physics&Chemistry, 2011,80(12):1358-1362.
[23]	Peng H, Chen H, Qu Y , et al. Bioconversion of different sizes of microcrystalline cellulose pretreated by microwave irradiation with/without NaOH[J]. Applied Energy, 2014,117(1):142-148. doi: 10.1016/j.apenergy.2013.12.002 URL
[24]	Hemvichian K, Chanthawong A, Suwanmala P . Synjournal and characterization of superabsorbent polymer prepared by radiation-induced graft copolymerization of acrylamide onto carboxymethyl cellulose for controlled release of agrochemicals[J]. Radiation Physics&Chemistry, 2014,103(5):167-171.
[25]	王挺 . 吸附层反应技术制备TiO/SiO纳米复合材料[D]. 杭州:浙江大学, 2007.
[26]	郭学涛 . 针铁矿/腐殖酸对典型抗生素的吸附及光解机理研究[D]. 广州:华南理工大学, 2014.
[27]	Gupta V K, Ali I . Chapter 2-Water treatment for inorganic pollutants by adsorption technology[M]. Environmental Water.Elsevier B. V. 2013.
[28]	Tao B, Fletcher A J . Metaldehyde removal from aqueous solution by adsorption and ion exchange mechanisms onto activated carbon and polymeric sorbents[J].Journal of Hazardous Materials, 2013, 244- 245(244-245C):240-250. doi: 10.1016/j.jhazmat.2012.11.014 URL
[29]	Dwivedi A D, Dubey S P, Hokkanen S , et al. Mechanistic investigation on the green recovery of ionic, nanocrystalline, and metallic gold by two anionic nanocelluloses[J]. Chemical Engineering Journal, 2014,253(1):316-324. doi: 10.1016/j.cej.2014.05.069 URL
[30]	Hokkanen S, Repo E, Sillanpää M . Removal of heavy metals from aqueous solutions by succinic anhydride modified mercerized nanocellulose[J]. Chemical Engineering Journal, 2013,223(3):40-47. doi: 10.1016/j.cej.2013.02.054 URL
[31]	岳文文 . 改性农用秸秆对水中硝酸根、磷酸根吸附效果的研究[D]. 济南:山东大学, 2007.
[32]	张洪锋 . 具有金属离子吸附功能的纳米纤维素微滤膜的制备[D]. 广州:华南理工大学, 2016.
[33]	黄沅清 . 改性纤维吸附剂的制备及对Cd2+和Pb2+的吸附性能研究[D]. 长沙:湖南大学, 2015.
[34]	Han W H, Dou Y . Microwave-assisted preparation of polyethyleneimine modified cellulose fiber and the adsorption performance of Cu~(2+))[J]. Environmental Engineering, 2016.
[35]	Sun X, Yang L, Li Q , et al. Amino-functionalized magnetic cellulose nanocomposite as adsorbent for removal of Cr(VI):Synjournal and adsorption studies[J]. Chemical Engineering Journal, 2014,241(1):175-183. doi: 10.1016/j.cej.2013.12.051 URL
[36]	Soto M L, Moure A, Domínguez H , et al. Recovery,concentration and purification of phenolic compounds by adsorption: A review[J]. Journal of Food Engineering, 2011,105(1):1-27. doi: 10.1016/j.jfoodeng.2011.02.010 URL
[37]	Barnthip N, Parhi P, Golas A , et al. Volumetric interpretation of protein adsorption:kinetics of protein-adsorption competition from binary solution[J]. Biomaterials, 2009,30(33):6495. doi: 10.1016/j.biomaterials.2009.08.016 URL
[38]	Dotto G L, Pinto L A . Adsorption of food dyes acid blue 9 and food yellow 3 onto chitosan:stirring rate effect in kinetics and mechanism[J]. Journal of Hazardous Materials, 2011,187(1-3):164. doi: 10.1016/j.jhazmat.2011.01.016 URL
[39]	Wang D C, Li Y H, Li D , et al. A review on adsorption refrigeration technology and adsorption deterioration in physical adsorption systems[J]. Renewable & Sustainable Energy Reviews, 2010,14(1):344-353.
[40]	Yu X, Tong S, Ge M , et al. Adsorption of heavy metal ions from aqueous solution by carboxylated cellulose nanocrystals[J]. Journal of Environmental Science, 2013,25(5):933-943. doi: 10.1016/s1001-0742(12)60145-4 URL pmid: 24218823
[41]	Low K S, Lee C K, Mak S M . Sorption of copper and lead by citric acid modified wood[J]. Wood Science and Technology, 2004,38(8):629-640. doi: 10.1007/s00226-003-0201-9 URL
[42]	Ahmed M. Donia, Ahmed M. Yousif, Asem A. Atia , et al. Preparation and Characterization of Modified Cellulose Adsorbents with High Surface Area and High Adsorption Affinity for Hg(II)[J]. Journal of Dispersion Science & Technology, 2014,35(3):380-389.
[43]	Zhou Y, Jin Q, Zhu T , et al. Separation of chromium (VI) from aqueous solutions by cellulose modified with D-glucose and quaternary ammonium groups[J]. Cellulose Chemistry Technology, 2012,46(5-6):319-329.
[44]	Maekawa E, Koshijima T . Properties of 2,3-dicarboxy cellulose combined with various metallic ions[J]. Journal of Applied Polymer Science, 2010,29(7):2289-2297. doi: 10.1002/app.1984.070290705 URL
[45]	密叶 . CMC吸水性纱布的制备与吸附性能研究[D]. 青岛:青岛大学, 2013.
[46]	Shen W, Chen S, Shi S , et al. Adsorption of Cu(II) and Pb(II) onto diethylenetriamine-bacterial cellulose[J]. Carbohydrate Polymers, 2009,75(1):110-114. doi: 10.1016/j.carbpol.2008.07.006 URL
[47]	Kalia S, Sabaa M W, Kango S . Polymer Grafting:A Versatile Means to Modify the Polysaccharides[M]. Bahra:Springer Berlin Heidelberg, 2013.
[48]	江嘉灏, 张洪锋, 王习文 . 改性纳米纤维素吸附材料的制备与表征[J]. 造纸科学与技术, 2017(1):7-11.
[49]	林春香 . 纤维素在离子液体中均相改性合成高性能吸附剂及结构可控的接枝共聚物[D]. 广州:华南理工大学, 2010.
[50]	Anirudhan T S, Nima J, Divya P L . Adsorption of chromium(VI) from aqueous solutions by glycidylmethacrylate-grafted-densified cellulose with quaternary ammonium groups[J]. Applied Surface Science, 2013,279(279):441-449. doi: 10.1016/j.jhazmat.2011.01.025 URL pmid: 21277080
[51]	Sabrine A, Sami B . Removal of organic pollutants from water by modified cellulose fibres[J]. Industrial Crops & Products, 2009,30(1):93-104. doi: 10.3390/ijerph15112419 URL pmid: 30384467
[52]	Yuan Z Y, Zhao F R . Study on Water Eutrophication and Biological Control[J]. China Rural Water & Hydropower, 2008.
[53]	Kim Y H, Hwang E D, Shin W S , et al. Treatments of stainless steel wastewater containing a high concentration of nitrate using reverse osmosis and nanomembranes[J]. Desalination, 2007,202(1-3):286-292. doi: 10.1016/j.desal.2005.12.066 URL
[54]	Wang W, Jin Z H, Li T L , et al. Preparation of spherical iron nanoclusters in ethanol-water solution for nitrate removal[J]. Chemosphere, 2006,65(8):1396. doi: 10.1016/j.chemosphere.2006.03.075 URL
[55]	Gašparovičová D, Králik M, Hronec M , et al. Supported Pd-Cu catalysts in the water phase reduction of nitrates: Functional resin versus, alumina[J]. Journal of Molecular Catalysis A Chemical, 2007,264(1-2):93-102. doi: 10.1016/j.molcata.2006.08.081 URL
[56]	吴文清, 黄少斌, 张瑞峰 , 等. 一种新型改性吸附剂对水中痕量磷的吸附特征[J]. 中国环境科学, 2012,32(11):1991-1998.
[57]	岳文文 . 改性农用秸秆对水中硝酸根、磷酸根吸附效果的研究[D]. 济南:山东大学, 2007.
[58]	李旺 . 木薯秸秆阴离子吸附剂的制备及对硝酸根吸附性能的研究[D]. 桂林:广西师范大学, 2012.
[59]	李志安, 林永标, 沈承德 , 等. 华南不同人工林土壤铵吸附特征及其吸附动力学研究[J]. 土壤学报, 2001,38(3):383-389.
[60]	Bhatti J . Influence of Oxalate and Soil Organic Matter on Sorption and Desorption of Phosphate onto a Spodic Horizon[J]. Soil Science Society of America Journal, 1989,62(4):1089-1095. doi: 10.2136/sssaj1998.03615995006200040033x URL
[61]	姜桂华 . 铵态氮在土壤中吸附性能探讨[J]. 建筑科学与工程学报, 2004,21(2):32-34.