4种氯制剂对养殖废水中高硝酸盐和亚硝酸盐的影响

doi:10.11924/j.issn.1000-6850.casb18120045

摘要/Abstract

摘要：

在高硝酸盐和亚硝酸盐养殖水体中添加一定浓度氯制剂,研究了漂白粉、漂粉精、强氯精和二氧化氯对养殖水体高亚硝酸盐和高硝酸盐消除能力的影响。结果发现：4种氯制剂对硝酸盐和亚硝酸盐消除都有显著性效果(P<0.05),水体中氨氮在试验过程中无显著变化,浓度为0.00 mg/L;二氧化氯组消除效果最明显,30 min时硝酸盐和亚硝酸盐的消除率高达99%、100%,处理组和空白组的硝酸盐浓度为(0.15±0.72)、(16.82±0.97) mg/L,亚硝酸盐浓度为(0.07±0.01)、(19.95±0.61) mg/L,强氯精次之,漂白粉效果最差,30 min时消除率分别为50%、38%,漂白粉和空白组硝酸盐的浓度为(8.49±0.66)、(16.82±0.97) mg/L,亚硝酸盐浓度为(12.33±0.48)、(19.95±0.6) mg/L;水体的pH值在试验后,各处理组都发生了显著的变化(P<0.05),空白组pH 7.63±0.10,强氯精和二氧化氯添加组,pH值都为降低趋势,二氧化氯组pH值降幅最大(pH 2.68±0.06),漂白粉和漂粉精添加组,pH值呈升高趋势,漂白粉组pH值升幅最大(pH 9.6)。通过本试验的研究,4种氯制剂在消除养殖废水中高亚硝酸盐效果显著,并且无氨氮累积,不产生二次污染物,对于养殖废水的处理排放及循环使用有重要意义。

关键词: 氯制剂, 亚硝酸盐, 硝酸盐, 集约化水产养殖, 养殖水体

Abstract:

A certain concentration of chlorine was added to the high nitrate and nitrite culture water to study the effects of bleaching powder, bleaching powder concentrated, strong chlorine and chlorine dioxide on the high nitrite and high nitrate elimination ability of the aquaculture water. The results showed that the four chlorine preparations had significant effects on the elimination of high nitrate and nitrite (P<0.05), and the ammonia nitrogen in the water did not change significantly during the test, the concentration was 0.00 mg/L; the elimination effect of chlorine dioxide group was the most obvious, the elimination rate of nitrate and nitrite was 99% and 100% at 30 min, and the nitrate concentration of the treatment group and the control group was (0.15±0.72) and (16.82±0.97) mg/L, nitrite concentration was (0.07±0.01) and (19.95±0.61) mg/L, followed by strong chlorine, and bleaching powder was the worst, the elimination rate was 50% and 38% at 30 min, respectively, and the nitrate concentration of the bleaching powder group and the control group was (8.49±0.66) and 16.82±0.97) mg/L, and the nitrite concentration was (12.33±0.48) and (19.95±0.6) mg/L. After the test, the pH value of the water changed significantly in each treatment group (P<0.05). The pH value of the control group was pH 7.63±0.10. The pH value of the strong chlorine and chlorine dioxide group showed a decreasing trend and the chlorine dioxide group decreased the most (pH 2.68±0.06), the pH value of the bleaching powder and bleaching powder concentrated group increased, and the pH value of the bleaching powder group increased the most (pH 9.6). In summary, the four kinds of chlorine preparations have significant effect on eliminating high nitrite in aquaculture wastewater, and there is no accumulation of ammonia nitrogen and no secondary pollutant, and the research is of great significance for the treatment, discharge and recycling of aquaculture wastewater.

Key words: chlorine preparation, nitrite, nitrate, intensive aquaculture, culture water

中图分类号:

S959

王博, 秦海鹏, 廖栩峥, 林秀玉, 胡世康, 孙成波. 4种氯制剂对养殖废水中高硝酸盐和亚硝酸盐的影响[J]. 中国农学通报, 2020, 36(9): 24-29.

Bo Wang, Haipeng Qin, Xuzheng Liao, Xiuyu Lin, Shikang Hu, Chengbo Sun. Effects of Four Chlorine Preparations on High Nitrate and Nitrite in Aquaculture Wastewater[J]. Chinese Agricultural Science Bulletin, 2020, 36(9): 24-29.

图/表 6

参考文献 22

[1]	韦宗敏, 王婷 . 硝酸盐去除途径浅析[J]. 广东化工, 2015,43(11):152-153.
[2]	Camargo J A, Alonso A . Ecological and toxicological effects of inorganic Nitrogen pollution in aquatic ecosystems: A glob-al assessment[J]. ENVIRON INT, 2006,32(6):831-849.
[3]	张霞霞, 李世森, 胡艺珂 , 等. 亚硝酸盐对水产动物毒性的影响[J]. 安徽农业科学, 2014(5):1398-1400.
[4]	余瑞兰, 聂湘平, 魏泰莉 . 分子氨和亚硝酸盐对鱼类的危害及其对策[J]. 中国水产科学, 1999,6(3):73.
[5]	王明学, 吴卫东 . NO₂ ^–N对鱼类毒性的研究概况 [J]. 中国水产科学, 1997,4(5):85-89.
[6]	白秀娟, 卢伙胜, 张冰 . 亚硝酸盐对茂名海域文昌鱼生长及磷酸酶的影响[J]. 水产科技, 2008,35(5):6-9.
[7]	魏泰莉, 余瑞兰, 聂湘平 , 等. 水中亚硝酸盐对彭泽鲫血红蛋白及高血红蛋白的[J]. 大连水产学院学报, 2001,16(1):68-70.
[8]	侯洪刚 . 硝酸盐对人体健康的影响及污染防治对策[J]. 现代农业, 2014,5:93-93.
[9]	Robinson-loraM A, BrennanR A . The use of crab-shell chitin for biological denitrification: Batch and column tests[J]. Bioresource Technology, 2009,100(2):534-541.
[10]	Law G, Parslow R, Mickinney P , et al. Non-Hodgkins lymphoma and nitratein drinking water: a study inYorkshire, United Kingdom[J]. Epidemiology Community Health, 1999,53:383-384.
[11]	Pelley J . Is coastal eutrophication out ofcontrol?[J]. Environmental Science and Technology, 1998,32(19):462A-466A.
[12]	Ahn J H , Kwang-Ho Choo K H, Park H S. Reverse osmosis membrane treatment of acidic etchant wastewater: effect of neutralization and polyelectrolyte coating on nitrate removal[J]. JMembrSci, 2008,310:296-302.
[13]	Rivett M O, Buss S R, Morgan P , et al. Nitrate attenuation ingroundwater:a review of biogeochemical controlling processes[J]. Water Res, 2008,42:4215-4232.
[14]	Wang Q H, Feng C P, Zhao, Y Z , et al. Denitrification of nitratecontaminated groundwater with a fiber-based biofilm reactor[J]. Bioresour Technol, 2009,100:2223-2227.
[15]	Prusse U, Vorlop K D . Supported bimetallic palladium catalystsfor water-phase nitrate reduction[J]. J MolCatal A:Chem, 2001,173:313-328.
[16]	Fan X M, Guan X H, Ma J , et al. Kinetics and corrosion productsof aqueous nitrate reduction by iron powder without reaction conditions control[J]. J Environ Sci, 2009,21:1028-1035.
[17]	Shin K H, Cha D K . Microbial reduction of nitrate in the presenceof nanoscale zero-valent iron[J]. Chemosphere, 2008,72:257-262.
[18]	Wang L, Sakamoto Y, Kamiya Y . Remediation of actual groundwater polluted with nitrate by the catalytic reduction over copper-palladium supported on active carbon[J]. ApplCatal A: Gen-eral, 2009,361:123-129.
[19]	Marchesini F A, Irusta S , QueriniC, et al. Nitrate hydrogenationover Pt,In/Al2O3and Pt,In/SiO2:effect of aqueous media and catalyst surface properties upon the catalytic activity[J]. CatalCommun, 0089:1021-1026.
[20]	Yoshinaga Y, Akita T, Mikami I , et al. Hydrogenation of nitrate inwater to nitrogen over Pd-Cu supported on active carbon[J]. JCatal, 2002,207:37-45.
[21]	唐玉朝, 凌先俊, 伍昌年, 尹汉雄 . 氧化法去除饮用水中亚硝酸盐氮的研究[J]. 应用化工, 2016,45(10):1845-1846.
[22]	赵琳, 王晓昌 . 紫外与次氯酸钠消毒效果及影响因素研究[J]. 环境污染与防治, 2014,36(7):41-45.