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中国农学通报

中国农学通报 ›› 2024, Vol. 40 ›› Issue (14): 54-63.doi: 10.11924/j.issn.1000-6850.casb2023-0456

• 农学·农业基础科学 • 上一篇    下一篇

苝二酰亚胺类光敏剂及其与氮磷钾叶面肥复配对油菜生长发育的影响

程澳华1(), 申江英1, 苏秀荣1, 孟娇2,3(), 孟庆羽2,3(), 洪丕征2,3, 王海卫2,3, 何利宁4   

  1. 1 山东农业大学化学院，山东泰安 271000
    2 山东农大肥业科技股份有限公司，山东泰安 271000
    3 农业农村部腐植酸类肥料重点实验室，山东泰安 271000
    4 泰安市农业技术推广中心，山东泰安 271000
  • 收稿日期:2023-06-13 修回日期:2023-12-18 出版日期:2024-05-15 发布日期:2024-05-09
  • 通讯作者:
    孟娇，女，1991年出生，山东曲阜人，高级工程师，博士，主要从事光功能材料的制备及其性能研究。通信地址：271600 山东泰安肥城创业路249号 山农大肥业科技股份有限公司，E-mail：。
    孟庆羽，男，1981年出生，山东泰安人，高级工程师，本科，主要从事化工工艺与新型肥料技术应用方面的研究。通信地址：271600 山东泰安肥城创业路249号 山农大肥业科技股份有限公司，E-mail：。
  • 作者简介:

    程澳华，女，1999年出生，山东菏泽人，在读硕士，主要从事新型肥料功能材料合成与应用方面的研究。通信地址：271000 山东泰安岱宗大街61号 山东农业大学化学与材料科学学院，E-mail：。

  • 基金资助:
    十四五国家重点研发计划项目“绿色缓控释及稳定性肥料工艺装备研发”(2022YFD1700602); 山东省重点研发计划项目“新型绿色农业投入品研发与示范”(2020CXGC010803)

Effect of Perylene Diimide Photosensitizers and Its Compound with Nitrogen, Phosphorus and Potassium Foliar Fertilizers on the Growth and Development of Rapeseed

CHENG Aohua1(), SHEN Jiangying1, SU Xiurong1, MENG Jiao2,3(), MENG Qingyu2,3(), HONG Peizheng2,3, WANG Haiwei2,3, HE Lining4   

  1. 1 College of Chemistry, Shandong Agricultural University, Tai’an, Shandong 271000
    2 Fertilizer Science Tech. Co., Ltd. of Shandong Agricultural University, Tai’an, Shandong 271000
    3 Key Laboratory of Humic Acid Fertilizer, Ministry of Agriculture and Rural Affairs, Tai’an, Shandong 271000
    4 Agricultural Technology Extension Center of Tai’an, Tai’an, Shandong 271000
  • Received:2023-06-13 Revised:2023-12-18 Published:2024-05-15 Online:2024-05-09

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摘要：

旨在研究苝二酰亚胺类光敏剂及其与氮磷钾叶面肥复配对油菜生长发育的影响，以1,7-二溴-3,4,9,10-苝四羧基双酐(PDI-2Br)为受体，环己胺为给体制备N,N’-二环己基-1,7-二环己胺基-3,4,9,10-苝二酰亚胺(PDI-4CHA)，随后在PDI-4CHA表面包裹纳米硅壳得到PDI-4CHA复合纳米胶囊（光敏剂，PS）。以油菜为试验材料，研究PS最佳喷施浓度，设置CK、0.4% PS、1.2% PS、2% PS、3% PS 5个处理；研究光敏剂与氮磷钾叶面肥W复配(PS&W)处理对油菜生长发育的影响，设置CK、叶面肥W、2% PS、0.4% PS&W、1.2% PS&W、2% PS&W 6个处理。结果表明：成功合成PDI-4CHA复合纳米胶囊；PS喷施浓度在0%~3%范围内，2% PS处理对油菜的促进效果最好，与CK相比，在最后一次取样中油菜SPAD值、干重、鲜重分别提高了21.93%、60.72%、44.93%；PS&W处理对油菜生长影响实验显示，相较于CK、W和PS处理，1.2% PS&W处理在最后一次取样中油菜的鲜重分别增高了161.43%、173.90%和105.46%，干重分别增高了163.98%、173.92%和107.64%，并且复配处理过的油菜的品质均不差于对照处理。该实验证明苝二酰亚胺类光敏剂及其与氮磷钾叶面肥复配喷施对油菜有增效作用。

关键词: 苝二酰亚胺, 光敏剂, 增效作用, 油菜

Abstract:

To study the effects of perylene diimide photosensitizers and its compound with nitrogen, phosphorus and potassium foliar fertilizers on the growth and development of rapeseed. N,N’-dicyclohexyl-1,7-dicyclohexylamine-3,4,9,10-perylenediimide (PDI-4CHA) was prepared using 1,7-dibromo-3,4,9,10-perylenetetracarboxylic dianhydride (PDI-2Br) as the acceptor and cyclohexylamine as the donor, and subsequently, PDI-4CHA composite nanocapsules (Photosensitizer, PS) were obtained by coating nanosilica on its surface. Rapeseed was used as the experimental material. Five treatments of CK, 0.4% PS, 1.2% PS, 2% PS and 3% PS were set up to investigate the optimal spraying concentration of PS, and six treatments of CK, foliar fertilizer W, 2% PS, 0.4% PS&W, 1.2% PS&W and 2% PS&W were set up to investigate the effects of the photosensitizer and nitrogen, phosphorus, and potassium foliar fertilizer W complex (PS&W) on the growth and development of rapeseed. The results showed that PDI-4CHA composite nanocapsules were successfully synthesized. 2% PS treatment had the best promotion effect on rapeseed when the spraying concentration ranged from 0% to 3%, and the SPAD value, dry weight, and fresh weight of rapeseed were increased by 21.93%, 60.72% and 44.93%, respectively, compared with CK in the last sampling. The experiments on the effect of PS&W treatment on the growth of rapeseed showed that, compared with CK, W and PS treatments, 1.2% PS&W treatment increased fresh weight by 161.43%, 173.90% and 105.46%, and dry weight was increased by 163.98%, 173.92% and 107.64%, respectively. What’s more, the quality of rapeseed treated with PS&W was not worse than that of the control treatment. The experiment proved that perylene diimide photosensitizer and its combination spraying with NPK foliar fertilizer had an efficient effect on rapeseed.

Key words: perylene diimide, photosensitizer, synergistic effect, rapeseed