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中国农学通报 ›› 2007, Vol. 23 ›› Issue (8): 515-515.

• 工程 机械 水利 装备 • 上一篇    下一篇

CTS-g-PAA/SH高吸水性树脂的缓释和保水性能

刘江华,,杨 逵,王爱勤   

  • 出版日期:2007-08-05 发布日期:2007-08-05

Slow-release and Water Absorbency Properties of Chitosan-g-poly(acrylic acid) /sodium Humate Superabsorbent

Liu Jianghua,, Yang Kui, Wang Aiqin   

  • Online:2007-08-05 Published:2007-08-05

摘要: 【研究目的】以壳聚糖(CTS)、丙烯酸(AA)和腐殖酸钠(SH)为原料,在水溶液中通过接枝共聚反应合成壳聚糖接枝聚丙烯酸/腐殖酸钠(CTS-g-PAA/SH)高吸水性树脂;【方法】考察CTS-g-PAA/SH树脂在不同浓度盐溶液中的溶胀行为、反复吸水性能、SH的缓释性能和在土壤中的实际保水效果;【结果】在SH含量为10%时,CTS-g-PAA/SH树脂在蒸馏水和生理盐水中的吸水倍率分别达到183g/g和41g/g;CTS-g-PAA/SH高吸水性树脂具有较好的反复吸水性能;与CTS-g-PAA相比,含有1.0%CTS-g-PAA/SH树脂的沙土,20d后仍然具有6.75%的保水率;SH能与AA发生聚合反应,形成网络结构,当SH含量超过30%时,过量的SH是以物理填充方式存在于高吸水性树脂的交联网络中,且容易释放;【结论】SH能改善CTS-g-PAA的吸水性,CTS-g-PAA/SH高吸水性树脂不仅可降低产品成本,而且还具有缓释腐殖酸的功能。

关键词: 蹄叶橐吾, 蹄叶橐吾, 菊科, 药理活性, 化学成分

Abstract: 【OBJECTIVE】A novel superabsorbent of chitosan-g-poly(acrylic acid)/sodium humate (CTS-g-PAA/SH) was synthesized through graft polymerization among chitosan, acrylic acid and sodium humate in aqueous solution. 【METHOD】The water absorbency in various saline solutions, resweling behaviors, the slow-release behavior of SH and the practical water absorbency in soil of CTS-g-PAA/SH superabsorbent were systematically investigated. 【RESULTS】The CTS-g-PAA/SH superabsorbent with 10% sodium humate gave water absorbency of 183g/g in distilled water and 41g/g in 0.9% NaCl solution. The CTS-g-PAA/SH superabsorbents have better reswelling behaviors. Comparing with CTS-g-PAA, 6.75% of water can still be saved in the sand soil containing 1.0% superabsorbent after 20 days. SH reacts with PAA during the polymerization process and forms a more intact polymeric network. When the SH content is above 30% in superabsorbent, the excess SH only acts as filler in the polymeric network and the slow-release of SH is easy.【CONCLUSION】Introducing SH could improve water absorbency of the CTS-g-PAA superabsorbent. CTS-g-PAA/SH superabsorbent not only can reduce significantly production cost, but also have slow-release capacity of humic acid.

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