Research Progress on Organic Acids in Tobacco

doi:10.11924/j.issn.1000-6850.2013-1274

Abstract

Abstract: The achievements about analysis of organic acids in tobacco at home and abroad over past years were reviewed comprehensively, and analyzed the properties and effects of various organic acids, such as volatile, semi-volatile and nonvolatile acids. Pretreatments of samples included solvent extraction, solid phase extraction, stream distillation, etc. Finally, this paper comprehensively introduced analysis of organic acids in tobacco about gas chromatography-mass spectrometry, high performance liquid chromatography (HPLC), ion chromatography (IC) and other methods. It was considered that it was possible to get a good understanding of various elements in smoke as the application and development of this modern separation technology and analysis equipment. And it provided factual basis for perfuming in tobacco industry.

References

[1] 闫克玉,等.烤烟国家标准(40级)河南烟叶水浸液 pH值,总酸度和总挥发酸含量研究[J].烟草科技,1997(4):16-18.
[2] Matsushima S, Ishiguro S, Sugawara S. Relationship between composition of tobacco essential oil and its aroma[J]. Nippon Noeikagaku,1980,54(12):1027-1035.
[3] 王瑞新.烟草化学[M].北京:中国农业出版社,2003:98-105.
[4] 周正红,高孔荣,张水华.烟草中化学成分对卷烟色香味品质的影响及其研究进展[J].烟草科技,1997(2):22-25.
[5] Weeks W. Chemistry of tobacco constituents influencing flavor and aroma[J]. Rec Adv in Tob Sci,1985(1):897-901.
[6] 高锦明,张鞍灵,张康健,等.绿原酸分布、提取与生物活性研究综述[J].西北林学院学报,1999,14(2):73-82.
[7] 钟庆辉.烟草芳香吃味化学指标的探索[J].烟草科技,1981(4): 21-23.
[8] Stedman R L. The chemical composition of tobacco and tobacco smoke [J].Chem Rev,1968,68:153-207.
[9] Kaburaki Y, Sato Y. Gas chromatographic analysis of volatile organic acids in tobacco leaves[J]. J Agr Chem Soc Japan,1962,36: 865-869.
[10] Stedman R L. Turkish tobacco substitute[P]. U.S. Patent:3180340, 1965-04-27.
[11] Lloyd R A, Miller C W, Robert D L, et al. Flue-cured tobacco flavor. I. Essence and essential oil components[J]. Tob Sci,1976: 40-48.
[12] Wahlberg I. Effects of flue-curing and aging on the volatile neutral and acidic constituents of Virginia tobacco[J]. Phytochemisty,1977, 16:1217-1235.
[13] Wahlberg I. Volatile basic constituents of Virginia tobacco[J]. Phytochemistry,1977,16:1233-1235.
[14] 王瑞新,马常力,韩峰,等.烤烟不同品种香气物质成分的定量分析[J].河南农业大学学报,1991(2):151-154.
[15] 刘百战,徐亮,詹建波,等.云南烤烟中非挥发性有机酸及某些高级脂肪酸的分析[J].中国烟草科学,1999(2):28-31.
[16] 李炎强,冼可法,赵明月,等.云南、河南烤烟中挥发性、半挥发性游离及结合态脂肪酸的研究[J].中国烟草学报,2000(1):1-6.
[17] 李炎强,胡有持,冼可法,等.烤烟叶片与烟梗挥发性、半挥发性酸性成分研究[J].中国烟草学报,2001,7(3):1-5.
[18] 闫克玉,李春松,闫洪洋,等.国产烤烟挥发酸含量的对比分析[J].烟草科技,2006(7):31-35.
[19] 胡建军,周冀衡,李文伟,等.烤烟香味成分与其感官质量的典型相关分析[J].烟草科技,2007(3):9-15.
[20] 薛超群,尹启生,王信民,等.烤烟烟叶香气质量与其常规化学成分的相关性[J].烟草科技,2006(9):27-30.
[21] Roberts D L, Rode W A. Isolation and identification of flavor components of burley tobacco[J]. Tob Sci,1972,16:107-112.
[22] Demole E, Berthet D. A chemical study of burley tobacco flavour (Nicotiana tabacum L.). Ⅰ.Volatile to medium-volatile constituents [J]. Helv Chim Acta,1972,55:1866-1882,
[23] Demole E, Berthet D. A chemical study of burley tobacco flavour (Nicotiana tabacum L.). Ⅱ.Medium-volatile, free acidic constituents [J]. Helv Chim Acta,1972,55:1898-1910.
[24] Fujimori T. Chemical studies on the aroma constituents in burley tobacco[J].Sci Papers, Cent Res Inst Japan Tobacco & Salt Public Corp,1976,118:85-119.
[25] Fujimori T. Neutral volatile components of burley tobacco[J].Beitr Tabakforsch,1978,9:317-325.
[26] 刘百战,宗若雯,岳勇,等.国内外部分白肋烟香味成分的对比分析[J].中国烟草学报,2000,6(2):1-5.
[27] 谢剑平,赵明月,吴鸣,等.白肋烟重要香味物质组成的研究[J].烟草科技,2002(10):3-16.
[28] Buyske Donald A. Volatile organic acids of tobacco smoke[J].Anal Chem,1955,27(6):928-931.
[29] Schmeltz I, Miller R L. Gas chromatography study of the stearm volatile fatty acids of various tobacco[J].J of G C,1963:27-28.
[30] Stedman R L. Composition studies on tobacco.ⅩⅥ.Steam-volatile acids[J].JAO A C,1963,46(5):779-784.
[31] Schumacher J N, Vestal L. Isolation and identification of some components of Turkish tobacco[J].Tob Sci,1974,18:43-48.
[32] Chuman T. Chemical studies on aroma constituents of Turkish tobacco[J].Sci Papers,Cent Res Inst Japan Tobacco & Salt Public Corp,1977,19:45-92
[33] Chuman T. Acidic aroma constituents of Turkish tobacco[J].Inter Congr Essential Oil,1977,7:435.
[34] Chuman T, Noguchi M. Acidic aroma constituents of Turkish tobacco[J]. Agric Biol Chem, 1977,41(6):1021-1030.
[35] 朱显灵,郑富钢,哈君利.世界香料烟生产形势分析[J].世界农业, 2006(11):31-33.
[36] 李云.气相色谱法分析中国烟叶的低级脂肪酸[J].烟草科技,1989 (3):27.
[37] 李云,毛若云,孙瑞申.一些中国烟叶低级脂肪酸的研究[J].中国烟草科学,1990(1):21-28.
[38] 刘国顺,符云鹏,刘学芝.不同产地和类型香料烟的化学成分研究[J].耕作与栽培,1996(1):28-31.
[39] 张燕,李天飞,宗会,等.不同产地香料烟内在化学成分及致香物质分析[J].中国烟草科学,2003(4):12-16.
[40] 韩延,刘国顺,刘艳英,等.不同生长期香料烟香气成分的变化动态研究[J].中国烟草科学,2003(2):41-45.
[41] 张永红,吴鸣,胡建军,等.国内外香料烟香味物质与品质比较[J].烟草科技,2004(1):3-7.
[42] 赵铭钦,韩富根,邵惠芳,等.香料烟浸膏香气物质成分研究[J].西北农林科技大学学报,2005(6):23-26.
[43] 陈章玉,毛义源,陈永宽,等.下低次烟综合运用——致香物质的提取分离[J].云南烟草,1996(4):53-57.
[44] 王昊阳,郭寅龙,张正行,等.自动化静态顶空-气相色谱-质谱对天然香精中挥发性化学成分的快速分析[J].分析测试学报,2004,23 (1):9-13.
[45] 孙志梅.动态顶空法分析烟草中的香味成分[J].淮南师范学院学报,2003,5(5):29-31.
[46] Kim K R. Isolation of essential oils from tobacco by gas co-distillation/solvent extraction[J].Chromatographia,1982,15(9): 559-563.
[47] 李炎强,冼可法.顶空共蒸馏法分析烟草中性香味成分[J].中国烟草学报,1997,3(3):1-9.
[48] Green J D, Payne B P. Reproducibility of simultaneous distillation-extraction techniques used in the isolation of volatiles compounds[A]. Anal Abs,1990,52(12):5-12.
[49] 杨叶昆,李雪梅,张晓龙,等.超临界流体萃取烟草浸膏中致香成分的研究[J].云南烟草,2003(3):39-44.
[50] 唐纲岭,刘惠民,李荣,等.固相微萃取/气相色谱/质谱法定性定量分析烟叶中香味物质的研究[J].中国烟草学报,2002(3):1-10.
[51] 鲁喜梅.卷烟主流烟气总粒相物中挥发性和半挥发性有机酸分析及其逐口递送规律研究[D].郑州:郑州大学,2006:1-66.
[52] 孙敏,杨金辉,张承聪,等.气相色谱直接测定烟样中有机酸含量[J].云南大学学报,2001,23(5):394-397.
[53] 李银科,李海燕,何顺琴,等.高效液相色谱法测定烟草中有机酸[J].工作简报,2011,47(1):64-67.
[54] 易娇,尹笃林,廉世勋,等.反相HPLC法同时测定烟草中的6种有机酸[J].烟草化学,2006,228(7):36-39.
[55] 杨忠乔,虞爱旭,侯镜德,等.气相色谱-质谱联用法分析烟丝中有机酸成分[J].分析测试技术与仪器,2003,9(1):38-42.
[56] 李莉,蔡群兰,蒋锦锋,等.全二维气相色谱/飞行时间质谱法分析烟草挥发和半挥发性酸性成分[J].烟草科技,2006,226(5):25-32.