Abstract: This paper is an experimental research about heavy metal Determination in Vegetable Soil in Suburb of Haerbin, Heilongjiang Province. When the determaination of heavy metals in Vegetable Soil by X-Ray Fluorescence Spectromtry 12 sammples were randomly selected and determined for five repeated experiments. Relative standard deviation of the results were all less than0.005％,0.006％,0.013％,0.003％ 和0.011％ of As,Cr,Cu,Pb,Zn,Compared with chemical method, the method of X-ray fluorescence spectrum has the advantages of the sampling being simple, the analytieal speed being quick,the result being accurate etc. The heavy metals in the sediment were determined by the method and the precision and reproducibity are in agreement with standard methods.The results of experiment show that this method may be used to determine heavy metals in the sediment．