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中国农学通报 ›› 2011, Vol. 27 ›› Issue (18): 268-272.

• 植物保护 农药 • 上一篇    下一篇

乙氧氟草醚光解动力学研究

李丽春 侯志广 万丽 逯忠斌   

  • 收稿日期:2011-03-28 修回日期:2011-05-09 出版日期:2011-07-25 发布日期:2011-07-25
  • 基金资助:

    农业部农药残留课题资助(2009H02)

Photolysis Kinetics of Oxyfluorfen

  • Received:2011-03-28 Revised:2011-05-09 Online:2011-07-25 Published:2011-07-25

摘要:

为了正确评价乙氧氟草醚在环境中的光解行为,建立了乙氧氟草醚在水溶液中的气相色谱分析方法,以高压汞灯为光源,研究了乙氧氟草醚在水溶液中的光降解情况。结果表明,在不同pH缓冲溶液中,乙氧氟草醚的光解速率为:pH 9>pH 7>pH 5,说明乙氧氟草醚在偏碱性环境中稳定性较差。乙氧氟草醚起始浓度对其光解有一定影响,光解数率随浓度增加而减小。其在pH 5、pH 7、pH 9的缓冲溶液中光解半衰期分别为63、20.69、13.67 min。为指导乙氧氟草醚的科学合理使用和正确评价乙氧氟草醚在水环境中的残留动态和安全效应提供科学依据。

关键词: 种子萌发, 种子萌发

Abstract:

Established the method of oxyfluorfen in different solutions by gas chromatography. Under the 500 W high pressure mercury lamp, photolysis of oxyfluorfen in buffer solution of different pH value, the results showed that the photolysis rate were quicker in pH 9 than that in other buffers and are in the order of pH 9>pH 7>pH 5, indicating the photolytic degradation of oxyfluorfen in alkaline solution, maybe result in poor stability. The experiments on influence of initial concentration on photolysis of oxyfluorfen under the 500 W high pressure mercury lamp showed that initial concentrations affected the photodegradation, and they make photolysis haf-life of oxyfluorfen decreased. The half-lives of oxyfluorfen in different buffers of pH 5, pH 7, pH 9 were 63, 20.69, 13.67 min。These can correctly appraise oxyfluorfen in the environment for the photodissociation behavior, as well as provide scientific basis for guiding oxyfluorfen science reasonable use and the correct evaluation in the residue of water environment polyether dynamic and safety effects provide the effective reference data.