Ozone Dissolution Characteristics and Removal Effect of Pesticide Residues in Cantaloupes by Ozone Water

doi:10.11924/j.issn.1000-6850.2014-0818

Abstract

Abstract: In order to investigate the effect of ozone treatment on pesticide degradation, this paper studied the ozone water solubility characteristics and the effect of different concentrations of ozone in water, different treatment times and different pH, different handling ways on cantaloupe which with four kinds of pesticide residues (malathion, chlorpyrifos, cypermethrin and chlorothalonil) degradation. The results showed that: the solubility of ozone decreased with increase of the volume of the absorbing solution and pH value, at pH 4 the solubility was up to 10.15 mg/L. With the increased of ozone concentration and immersion time, the degradation of 4 kinds of pesticide residues at different degree rate increased in cantaloupe. Degradation rate of dynamic ozone water was significantly higher than the static ozone water treatment (P＜0.05). Best result was obtained in pH 10 dynamic ozone water treatment for 30 min, malathion, chlorpyrifos, cypermethrin, chlorothalonil degradation rate of four pesticides were 90.87%, 85.62%, 78.31% and 85.26%.

References

[1] 孙芳晓.哈密瓜金海蜜无土栽培技术[J].农业科技通讯,2011,23(6): 23-24.
[2] 中华人民共和国卫生部中华人民共和国农业部.GB 2763—2012,食品安全国家标准食品中农药最大残留限量[S].北京:中国质检出版社,2012:1-90.
[3] 乔彩云,李建科,李梦颖,等.臭氧在水中的溶解和消除特性及其对苹果青霉的杀菌效果[J].食品科学,2012,33(19):79-83.
[4] Walter R H, Sherman R M. Duration of ozone in water in the upper solubility range[J]. Journal of food science,1976,5(41):993-995
[5] 孙广明,李宝华,李汉忠.臭氧特性及对水质的净化作用[J].渔业现代化,2000,13(4):23.
[6] 王华然,王尚,李昀桥等.臭氧在水中的溶解特性及其影响因素研究[J].中国消毒学志,2009,5(17):481-483.
[7] Gurol Mirat D. Kinetics of ozone decomposition: A dynamic approach[J]. Environ Sci Technol,1982,16(7):380
[8] 杨挺,陆胜民.臭氧降解蔬菜中拟除虫菊酯类农药及其对蔬菜品质的影响[J].食品工业科技,2007,1(28):213.
[9] 徐慧,蒋栋磊,张银志,等.臭氧降解 8种蔬菜中农药残留研究[J].食品工业科技,2012,22(33):75-77.
[10] 曾令琴,陈芳,吴继红,等.臭氧水降解苹果表面有机磷农药的研究[J].食品与发酵工业,2006,32(2):16-19.
[11] 王长方,陈峰,魏辉.甘蓝中高效氯菊酯残留去除方法的研究[J].农业环境科学学报,2005,24(5):1018-1021.
[12] 詹萍,田洪磊.臭氧降解苹果中克菌丹农药残留技术研究[J].食品科学,2008,29(10):183-186.
[13] 伍小红,臭氧对苹果的贮藏保鲜及农药残留降解作用的研究[D].陕西:陕西师范大学,2006:34-38.
[14] 仇农学,陈颖.臭氧溶解特性及对耐热菌非热杀菌的研究[J].农业工程学报,2004,20(4):157-159.
[15] 白敏东,沈丽,左军,等.取得高溶解率和高浓度臭氧水的方法[J].水处理技术,2001,27(1):42-44.
[16] 代欣欣,李汴生.水中臭氧溶解特性的研究[J].食品科技,2008(8): 84-87.
[17] 韩德刚.物理化学[M].北京:高等教育出版社,2001:145
[18] Tomijas H, Fukutomi H, Gordon G. Kinetics and mechanism of ozone decomposition in basic aqueous solution[J]. Inony Chem, 1985(24):2962-2966.
[19] Fornol D Bahnemann, Edwin J Hart. Mechanism of the hydroxide ion intiated decomposition of ozone in aqueous solution[J]. Phys Chem,1982,86:255-259.
[20] 方敏,沈月新,方竞,等.臭氧水稳定性的研究[J].食品科学,2002,9 (14):39-43.
[21] 王多加,胡祥娜,禹绍周,等.臭氧对蔬菜中农药残留降解效果的研究[J].现代科学仪器,2003,1(6):47-49.
[22] 刘芳,李友广.臭氧对有机磷农药残留降解效果及检测方法的研究[J].食品工业科技,2008,4(12):245-247.
[23] 杨梅,徐小军,桂文君,等.臭氧水对黄瓜和青菜中 6种有机磷农药残留的去除效果[J].农药学学报,2013,1:85-90.
[24] 蒋红英,刘书来,张建友,等.有机磷和菊酯类农药在蔬菜中的氧化消降技术研究[J].浙江工业大学学报,2010,4(20):368-371.
[25] 胡冰.超声强化臭氧化处理水中有机磷农药的研究[D].黑龙江:大庆石油学院,2006:29-35.
[26] Von Gunten U． Ozonation of drinking water: part I． Oxidation kinetics and product formation[J]. Water Res,2003,37(7):1443-1467.
[27] Qiang Z, Adams C, Surampalli R. Determination of ozonation rate constants for lincomycin and spectinomycin[J]. Ozone Sci Eng, 2004,26(6):525-537.