Effect of Passivation Agent on Morphology and Stability of Heavy Metals in Cropland Soil

doi:10.11924/j.issn.1000-6850.casb15070042

Abstract

Abstract: Due to its low processing cost, fast effect, simple operation and no harm to crop production, passivation agent has attracted extensive attention. The common types of passivation agent include lime material, carbon material, clay minerals, phosphorus materials, organic fertilizer and so on. The application of passivation agent could change exchangeable state of heavy metals, carbonate bound state, Fe-Mn oxide bound state, organic matter binding state and residue state to reduce bio-availability. Different kinds of passivation agent had different effects on the stability of heavy metals. The passivation agent applied in high contaminated soil might be saturated by pollutants, led to a limited passivation capacity. The passivation effect became weaker with the increase of time. The effect of passivation agent on the stability uration time of heavy metal morphology still need to be studied.

References

[1]韦朝阳,陈同斌.2001.重金属超富集植物及植物修复技术研究进展[J].生态学报,2001,21(7):1196-1203.
[2] 王立群,罗磊,马义兵,等.重金属污染土壤原位钝化修复研究进展[J].应用生态学报,2009, 20(5):1214-1222
[3] 周航,周歆,曾敏,等.2种组配改良剂对稻田土壤重金属有效性的效果[J].中国环境科学,2014,34(2)：437-444.
[4] 韩春梅,王林山,巩宗强,等.土壤中重金属形态分析及其环境学意义[J].生态学杂志,2005,24(12)：1499-1502.
[5] 钱进,王子健,单孝全,等.土壤中微量金属元素的植物可给性研究进展[J].环境科学,1995,16(6)：73-75,78.
[6] Susan E.,Bailey H.,Trudy J.,etal.A review of potentially low-cost sorbents for heavy metals.Water Reasearch,1998,33(11):2469-2479.
[7]Tessier A. 1979 . Sequential extraction procedure for the speciation of particulate , trace metals[J ] . Anal . Che m . ,51 ( 7) : 844～851.
[8] 邵孝侯,邢光熹.1994.连续提取法区分土壤重金属元素形态的研究及应用[J] . 土壤学进展 , 22 ( 3) : 1～2.
[9] 党秀丽,陈彬,虞娜,等.温度对外源性重金属镉在土一水界面间形态转化的影响[J].生态环境, 2007, l6 (3): 794-79.
[10] 韩照祥,吕春霞,朱莉娜.海洋沉积物对铅吸附行为的研究[J].水利渔业, 2007, 27 (2): 86-88.
[11] 廖敏,黄昌勇,谢正苗. pH对镉在土水系统中的迁移和形态的影响[J].环境科学学报, 1999, 19(1): 81-86.
[12] 刘清,王子健,汤鸿宵.重金属形态与生物毒性及其生物有效性关系的研究进展[J]. 环境科学, 1996, 17(1): 89-92.
[13] 林美群, 马少健, 王桂芳, 等. 环境因素对硫化矿尾矿重金属溶出影响的模拟试验[J]. 金属矿山, 2008, (6): 108-112.
[14] 曹心德, 魏晓欣, 代革联, 等.土壤重金属复合污染及其化学钝化修复技术研究进展[J].环境工程学报, 2011,5(7):1441-1453.
[15] 徐露露,马友华,马铁铮,等.钝化剂对土壤重金属修复研究进展[J].农业资源与环境学报,2013,30(6)：25-29.
[16]Lombi E.,Hamon R.E.,McGrath S.P.,etal.Lability of Cd,Cu,and Znin polluted soils treated with lime,beringite,and red mud and identification of a non-labile colloidal fraction of metals using isotopic techniques.Environmental Science and Technology,2003,37(5):979-984.
[17]Singh B.R.,Oste L.In situ immoboilization of metals in contaminated or naturally metal-rich soils.Environmental Review,2001,9(2):81-97.
[18] Singh A K , Benerjee D K. 1999 . Grain size and geochemical partitioning of heavy metals in sediments of the Damodar River - A tributary of the lower Ganga ,India [J ] . Environ . Geol . , 39 ( 1) :91～98.
[19] 刘永红,姜冠杰,杨海征,等.土壤重金属污染及其修复技术研究进展[J].环境污染治理技术与设备, 2007, 3(7): 51- 55.
[20] COTTER—HOWELLS J,CAPOM S．Remediation of contaminated land by formation of heavy metal phosphates [J]．Applied Geochemistry,1996,11(1/2)：335-342.
[21] 刘霞,刘树庆,王胜爱,等. 2003 .河北主要土壤中Cd和Pb的形态分布及其影响因素[J ] .土壤学报, 40 ( 3) : 393～401
[22] 杨宏伟,王明仕,徐爱菊,等. 2001 .黄河(清水河段)沉积物中锰、钴、镍的化学形态研究[J ].环境科学研究, 14 (5) : 20～22
[23]丁疆华,温琰茂,舒强,等. 2001 .土壤环境中镉、锌形态转化的探讨[J].城市环境与城市生态,14(2):1～10
[24] 李宗利.1994.污灌土壤中Pb、Cd形态的研究[J].农业环境保护,2(4):152～157
[25]Wiese SBO,Macleod CL,Lester JN.1997.A recent history of metal accumulation in the sediments of the Thames Estuary,United Kingdom[J].Estuaries,20(3):483～493
[26] 杨志新,冯圣东,刘树庆.镉、锌、铅单元素及其复合污染与土壤过氧化氢酶活性关系的研究[J].中国生态农业学报,2005,13(4):138-141
[27] 马铁铮,马友华,徐露露,等.农田土壤重金属污染的农业生态修复技术[J].农业环境科学学报,2013,30(5):39-43
[28] 郑少玲,陈琼贤,马磊,等.施用生物有机肥对芥蓝及土壤重金属含量影响的研究[J].农业环境科学学报,2005,24(Z1):62-66.
[29] 孙敬亮,武文钧,赵瑞雪,等.2003.重金属土壤污染及植物修复技术[J].长春理工大学学报, 2003,26(4):46-48
[30] 杨元根, Paterson E,Canp bell C. 2001 . 城市土壤中重金属元素的积累及微生物效应[J].环境科学,22(3):44～48
[31] 何飞飞, 曾建兵, 吴爱平, 等. 改良剂修复利用镉污染菜地土壤的田间效应研究[J]. 中国农学通报, 2012, 28(31): 247-251.
[32] 黎大荣, 吴丽香, 宁晓君,等.不同钝化剂对土壤有效态铅和镉含量的影响[J].环境保护科学,2013, 39(3):46-49.
[33] 王汉卫, 王玉军, 陈杰华, 等. 改性纳米碳黑用于重金属污染土壤改良的研究[J]. 中国环境科学, 2009, 29(4): 431~436
[34] 袁敏,铁柏清,唐美珍,等.改良剂对铅锌尾矿污染土壤上龙须草生长和叶片叶绿素含量的影响[J].农村生态环境,2005,21(4):54-57
[35] 王林,徐应明,孙扬,等.海泡石及其复配材料钝化修复镉污染土壤[J].环境工程学报,2010,4(9):2093-2098
[36] 朱奇宏,黄道友,刘国胜,等.石灰和海泡石对镉污染土壤的修复效应与机理研究[J].水土保持学报,2009, 23(1): 111-116
[37] Liang B, Lehmann J, Solomom D, et al. Black carbon increases canon exchange capacity in soils [J]. Soil Science Society of America Journal, 2006, 70:1719-1730.
[38] 周世伟, 徐明岗. 磷酸盐修复重金属污染土壤的研究进展[J]. 生态学报, 2007,27(7):3043-3050.
[39] Cao X. D., Ma L. Q., Singh S. P., et al． Phosphate-induced lead immobilization from different lead minerals in soils under varying pH conditions[J]. Environment Pollution, 2008, 152(1): 184-192.
[40] Begum Z A,Rahman I M M,Tate Y,等.Remediation of toxic metal contaminated soilbywashingwithbiodegradableaminopoly-carboxylatecgelants[J].Chemosphere,2012,87(10):1161-1170.
[41] 陈梦舫, 罗飞, 韩璐等. 污染场地健康与环境风险评估软件(著作权登记号：2012SR118710). 中国科学院南京土壤研究所污染场地修复中心, 南京, 2012.