Analysis of Aroma Components in Six Martagon Hybrids Varieties

doi:10.11924/j.issn.1000-6850.casb2025-0782

Abstract

Abstract:

To detect the floral aroma components of 6 martagon hybrids varieties, SPME/GC-MS technology was used to analyze and identify the volatile components in their flowers. 26 aroma components were detected in the 6 martagon hybrids varieties, including 12 monoterpenes, 5 fatty acid derivatives, 3 alkanes, 3 benzenoids/phenylpropanoids, and 3 heterocycles compounds. ‘Arabian Knight’, ‘Claude Shride’, ‘Peppard Gold’, ‘Alberta Morning’, ‘Pink Morning’, and ‘Snowy Morning’ had 15, 19, 22, 19, 23, and 20 aroma components, respectively. Among them, the main aroma components of ‘Arabian Knight’ and ‘Peppard Gold’ were linalool and eucalyptol; the main aroma components of ‘Claude Shride’ were linalool, nonanal, and 4-terpineol; the main aroma components of ‘Alberta Morning’ were α-thujene and linalool; the main aroma components of ‘Pink Morning’ were linalool, benzaldehyde, and α-thujene; and the main aroma component of ‘Snowy Morning’ was eucalyptol.

Key words: martagon hybrids, floral scent, aroma components, headspace solid phase microextraction, gas chromatography-mass spectrometry

CLC Number:

S682.2

DU Wenwen, YANG Yahui, SUN Jianli, LI Xiang, MA Lan, DUAN Qing, CUI Guangfen. Analysis of Aroma Components in Six Martagon Hybrids Varieties[J]. Chinese Agricultural Science Bulletin, 2026, 42(13): 73-78.

Figures/Tables 5

References 27

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类别	编号	化合物	保留时间/ min	保留指数	矫正保留指数	分子式	CAS	相对含量/%
类别	编号	化合物	保留时间/ min	保留指数	矫正保留指数	分子式	CAS	阿拉伯骑士	克劳德·施赖德	帕德黄金	阿尔伯塔清晨	粉色清晨	白雪清晨
烷烃类	1	癸烷	11.15	1000	995	C₁₀H₂₂	124-18-5	1.02±0.23	2.12±0.47	—	2.23±0.32	—	—
	2	十二烷	19.26	1200	1199	C₁₂H₂₆	112-40-3	8.59±2.17	18.3±1.43	12.54±0.70	16.07±3.44	9.13±1.53	6.46±1.16
	3	十三烷	22.38	1300	1299	C₁₃H₂₈	629-50-5	4.10±0.42	8.97±1.06	9.91±1.13	11.13±1.34	6.25±1.02	5.85±1.04
单萜类	1	α-侧柏烯	8.12	929	919	C₁₀H₁₆	2867-5-2	—	2.93±0.95	3.86±0.73	10.16±1.09	9.06±2.32	7.25±0.62
	2	蒎烯	8.25	929	922	C₁₀H₁₆	7785-70-8	—	1.16±0.33	1.59±0.52	1.88±0.53	1.92±0.24	2.53±0.54
	3	桧烯	9.95	974	965	C₁₀H₁₆	3387-41-5	—	—	1.60±0.19	2.53±0.73	1.73±0.35	—
	4	月桂烯	10.75	991	985	C₁₀H₁₆	123-35-3	5.95±0.46	1.31±0.56	2.21±0.04	2.54±0.21	2.16±0.23	2.10±0.97
	5	柠檬烯	12.36	1030	1023	C₁₀H₁₆	138-86-3	4.98±0.21	1.73±0.29	3.86±0.43	3.93±0.36	3.38±0.93	4.20±1.08
	6	桉叶油醇	12.46	1032	1025	C₁₀H₁₈O	470-82-6	11.18±1.55	5.03±1.14	9.79±2.19	8.42±1.06	6.15±1.55	29.36±3.56
	7	罗勒烯	12.89	1038	1035	C₁₀H₁₆	3338-55-4	5.15±1.45	—	1.64±0.49	—	0.80±0.11	1.69±0.57
	8	γ-松油烯	13.76	1060	1055	C₁₀H₁₆	99-85-4	—	5.40±1.9	3.60±0.92	6.77±0.80	5.66±0.86	6.85±0.72
	9	顺-4-侧柏醇	14.11	1070	1064	C₁₀H₁₈O	15537-55-0	—	3.14±1.08	—	3.11±0.39	2.99±0.76	2.66±0.54
	10	芳樟醇	15.58	1099	1098	C₁₀H₁₈O	78-70-6	21.77±1.14	13.81±1.77	13.68±0.68	10.60±1.06	15.36±1.47	8.45±1.88
	11	4-萜烯醇	18.43	1177	1176	C₁₀H₁₈O	562-74-3	—	8.66±1.98	3.60±0.86	3.94±1.43	5.10±0.73	5.15±0.49
	12	α-松油醇	18.90	1189	1189	C₁₀H₁₈O	98-55-5	5.25±1.29	1.20±0.28	1.29±0.19	0.79±0.06	0.90±0.40	—
苯环/ 苯丙素类	1	对二甲苯	6.05	865	855	C₈H₁₀	106-42-3	5.45±1.47	6.72±0.89	2.83±0.53	3.10±0.28	2.99±0.95	1.57±0.54
	2	苯甲醛	9.55	962	955	C₇H₆O	100-52-7	8.28±0.59	2.71±0.77	5.08±1.06	—	9.07±0.64	2.09±0.81
	3	邻-异丙基苯	12.18	1022	1019	C₁₀H₁₄	527-84-4	—	2.73±1.41	1.52±0.39	2.71±0.28	1.62±0.45	1.66±0.26
脂肪酸衍生物类	1	乙酸异戊酯	6.67	876	876	C₇H₁₄O₂	123-92-2	—	1.74±0.52	4.32±1.78	3.71±0.70	3.83±1.18	—
	2	乙酸己酯	11.83	1011	1011	C₈H₁₆O₂	142-92-7	7.95±0.66	—	—	—	—	—
	3	乙酸反-2-己烯酯	12.08	1016	1017	C₈H₁₄O₂	2497-18-9	4.36±0.52	—	—	—	—	—
	4	壬醛	15.76	1104	1102	C₉H₁₈O	124-19-6	4.10±0.83	9.40±2.36	6.49±1.54	4.20±0.33	4.54±1.61	4.05±0.55
	5	癸醛	19.45	1206	1205	C₁₀H₂₀O	112-31-2	1.87±0.54	2.93±1.71	2.74±0.8	2.16±0.51	1.65±0.71	1.54±0.12
杂环类	1	丁香醛A	17.21	1145	1142	C₁₀H₁₆O₂	53447-46-4	—	—	3.30±0.73	—	1.78±0.56	2.79±0.62
	2	丁香醛B	17.51	1154	1150	C₁₀H₁₆O₂	53447-45-3	—	—	2.52±0.55	—	2.98±0.12	2.46±0.65
	3	丁香醇A	19.63	1211	1210	C₁₀H₁₈O₂	33081-34-4	—	—	2.03±0.56	—	0.98±0.20	1.30±0.27

类别	编号	化合物	保留时间/ min	保留指数	矫正保留指数	分子式	CAS	相对含量/%
类别	编号	化合物	保留时间/ min	保留指数	矫正保留指数	分子式	CAS	阿拉伯骑士	克劳德·施赖德	帕德黄金	阿尔伯塔清晨	粉色清晨	白雪清晨
烷烃类	1	癸烷	11.15	1000	995	C₁₀H₂₂	124-18-5	1.02±0.23	2.12±0.47	—	2.23±0.32	—	—
	2	十二烷	19.26	1200	1199	C₁₂H₂₆	112-40-3	8.59±2.17	18.3±1.43	12.54±0.70	16.07±3.44	9.13±1.53	6.46±1.16
	3	十三烷	22.38	1300	1299	C₁₃H₂₈	629-50-5	4.10±0.42	8.97±1.06	9.91±1.13	11.13±1.34	6.25±1.02	5.85±1.04
单萜类	1	α-侧柏烯	8.12	929	919	C₁₀H₁₆	2867-5-2	—	2.93±0.95	3.86±0.73	10.16±1.09	9.06±2.32	7.25±0.62
	2	蒎烯	8.25	929	922	C₁₀H₁₆	7785-70-8	—	1.16±0.33	1.59±0.52	1.88±0.53	1.92±0.24	2.53±0.54
	3	桧烯	9.95	974	965	C₁₀H₁₆	3387-41-5	—	—	1.60±0.19	2.53±0.73	1.73±0.35	—
	4	月桂烯	10.75	991	985	C₁₀H₁₆	123-35-3	5.95±0.46	1.31±0.56	2.21±0.04	2.54±0.21	2.16±0.23	2.10±0.97
	5	柠檬烯	12.36	1030	1023	C₁₀H₁₆	138-86-3	4.98±0.21	1.73±0.29	3.86±0.43	3.93±0.36	3.38±0.93	4.20±1.08
	6	桉叶油醇	12.46	1032	1025	C₁₀H₁₈O	470-82-6	11.18±1.55	5.03±1.14	9.79±2.19	8.42±1.06	6.15±1.55	29.36±3.56
	7	罗勒烯	12.89	1038	1035	C₁₀H₁₆	3338-55-4	5.15±1.45	—	1.64±0.49	—	0.80±0.11	1.69±0.57
	8	γ-松油烯	13.76	1060	1055	C₁₀H₁₆	99-85-4	—	5.40±1.9	3.60±0.92	6.77±0.80	5.66±0.86	6.85±0.72
	9	顺-4-侧柏醇	14.11	1070	1064	C₁₀H₁₈O	15537-55-0	—	3.14±1.08	—	3.11±0.39	2.99±0.76	2.66±0.54
	10	芳樟醇	15.58	1099	1098	C₁₀H₁₈O	78-70-6	21.77±1.14	13.81±1.77	13.68±0.68	10.60±1.06	15.36±1.47	8.45±1.88
	11	4-萜烯醇	18.43	1177	1176	C₁₀H₁₈O	562-74-3	—	8.66±1.98	3.60±0.86	3.94±1.43	5.10±0.73	5.15±0.49
	12	α-松油醇	18.90	1189	1189	C₁₀H₁₈O	98-55-5	5.25±1.29	1.20±0.28	1.29±0.19	0.79±0.06	0.90±0.40	—
苯环/ 苯丙素类	1	对二甲苯	6.05	865	855	C₈H₁₀	106-42-3	5.45±1.47	6.72±0.89	2.83±0.53	3.10±0.28	2.99±0.95	1.57±0.54
	2	苯甲醛	9.55	962	955	C₇H₆O	100-52-7	8.28±0.59	2.71±0.77	5.08±1.06	—	9.07±0.64	2.09±0.81
	3	邻-异丙基苯	12.18	1022	1019	C₁₀H₁₄	527-84-4	—	2.73±1.41	1.52±0.39	2.71±0.28	1.62±0.45	1.66±0.26
脂肪酸衍生物类	1	乙酸异戊酯	6.67	876	876	C₇H₁₄O₂	123-92-2	—	1.74±0.52	4.32±1.78	3.71±0.70	3.83±1.18	—
	2	乙酸己酯	11.83	1011	1011	C₈H₁₆O₂	142-92-7	7.95±0.66	—	—	—	—	—
	3	乙酸反-2-己烯酯	12.08	1016	1017	C₈H₁₄O₂	2497-18-9	4.36±0.52	—	—	—	—	—
	4	壬醛	15.76	1104	1102	C₉H₁₈O	124-19-6	4.10±0.83	9.40±2.36	6.49±1.54	4.20±0.33	4.54±1.61	4.05±0.55
	5	癸醛	19.45	1206	1205	C₁₀H₂₀O	112-31-2	1.87±0.54	2.93±1.71	2.74±0.8	2.16±0.51	1.65±0.71	1.54±0.12
杂环类	1	丁香醛A	17.21	1145	1142	C₁₀H₁₆O₂	53447-46-4	—	—	3.30±0.73	—	1.78±0.56	2.79±0.62
	2	丁香醛B	17.51	1154	1150	C₁₀H₁₆O₂	53447-45-3	—	—	2.52±0.55	—	2.98±0.12	2.46±0.65
	3	丁香醇A	19.63	1211	1210	C₁₀H₁₈O₂	33081-34-4	—	—	2.03±0.56	—	0.98±0.20	1.30±0.27