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中国农学通报 ›› 2017, Vol. 33 ›› Issue (5): 66-71.doi: 10.11924/j.issn.1000-6850.casb16050112

• 资源 环境 生态 土壤 气象 • 上一篇    下一篇

芦根表面铁氧化物对水体中五价砷吸附性能的研究

赵纪舒,赵寅捷,耿丽平.,孙洪欣.,薛培英.   

  1. 河北保定一中,北京十一学校,河北农业大学资源与环境科学学院,河北农业大学资源与环境科学学院,河北农业大学资源与环境科学学院
  • 收稿日期:2016-05-18 修回日期:2017-01-05 接受日期:2016-07-21 出版日期:2017-03-01 发布日期:2017-03-01
  • 通讯作者: 薛培英.
  • 基金资助:
    河北省高等学校创新团队领军人才培育计划(LJRC016)

Pentavalent Arsenic Adsorption Ability of Iron Oxides Formed on Reed Root Surface in Water

  • Received:2016-05-18 Revised:2017-01-05 Accepted:2016-07-21 Online:2017-03-01 Published:2017-03-01

摘要: 芦苇是多年生湿地植被,其根系具有向根际环境释放氧气和氧化性物质,并在根表和根际形成铁氧化物膜状包被的特性。本文针对芦苇根表生物成因的铁氧化物具有两性胶体的性质,以直接和高温炭化得到的芦根表面的铁氧化物为吸附材料,采用等温平衡法研究了该吸附材料对外部溶液中五价砷的吸附效果。结果表明,在酸性条件下芦根根表获取的铁氧化物对五价砷的吸附能力明显强于中性及碱性条件;两种方式获取的铁氧化物材料对砷的吸附性能如下:随着外部介质溶液中砷添加浓度的增加,铁氧化物材料对砷的吸附量逐渐增加,最高可达16.70 mg.g-1,但并未达到铁氧化物的最大吸附量平台。由此可见,生物成因的铁氧化物材料对五价砷有很强的吸附能力。综合考虑芦根根表铁氧化物对砷的吸附能力及其对处理砷污染水体的可行性,且该生物成因材料的高温炭化处理方式优于直接获取的处理方式。

关键词: 茶树栽培, 茶树栽培, 文献计量学, 分析, 评价

Abstract: Reed is perennial wetland vegetation, whose root has the ability to release oxygen and oxidants into the rhizosphere, and form iron oxides at the root surface or rhizosphere. According to the amphoteric colloid ability of reed root biogenic iron oxides, the iron oxides were used as adsorbing material obtained by the methods of both direct obtaining and high temperature carbonization, the adsorption effect of this material to pentavalent arsenic [As (V)] was studied by isotherm method. The results showed that the As (V) adsorption ability of iron oxides under acidic condition was significantly higher than that in neutral or alkaline condition. The adsorption content increased with the increase of As concentration in the external medium solution, when the As concentration was 200 mg/L, the adsorption content of two iron oxides treatments reached (17.00±3.25) and (12.82±1.01) mg/g, respectively. The adsorption of As by iron oxides could be well described by Langmuir and Freundlich isothermal adsorption model. The maximum adsorption amounts of As obtained by Langmuir isotherm equation were (17.72±1.09) and (21.94±6.74) mg/g, respectively. Therefore, the biogenic iron oxides had strong absorption ability to As (V). Overall consideration of the adsorption ability and the feasibility of polluted water management, iron oxides treated by high temperature carbonization were better than that of direct obtaining.

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