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中国农学通报 ›› 2019, Vol. 35 ›› Issue (8): 39-45.doi: 10.11924/j.issn.1000-6850.casb18030096

所属专题: 水产渔业

• 资源 环境 生态 土壤 气象 • 上一篇    下一篇

电化学法处理养殖粪便重金属的研究

熊长齐1, 李掎琛2, 吴燿嶷1, 雷 鸣1   

  1. 1.湖南农业大学资源环境学院;2.湘潭大学材料科学与工程学院
  • 收稿日期:2018-03-19 修回日期:2018-05-23 接受日期:2018-06-06 出版日期:2019-03-15 发布日期:2019-03-15
  • 通讯作者: 雷 鸣
  • 基金资助:
    农业部、财政部“灌溉水源水质净化技术试点研究”(农办财函〔2015〕38 号);湖南省大学生研究性学习和创新性实验计划项目“电化学处 理养殖粪便中的重金属”(SCX1619)。

Removal of Heavy Metal From Livestock Manure Using Electroreduction Method

  • Received:2018-03-19 Revised:2018-05-23 Accepted:2018-06-06 Online:2019-03-15 Published:2019-03-15

摘要: 对浏阳市永安镇某养殖场养殖粪便中Cu2+、Zn2+、Cd2+、Pb2+等重金属离子的含量进行了分析,并以石墨板为阳极、不锈钢板为阴极的电化学方法对养殖粪便进行处理,考察了电解电压、电解时间等因素,对样品不同区域pH以及Cu2+、Zn2+、Cd2+、Pb2+等重金属离子处理效果的影响,同时计算能源消耗费用。结果表明,阳极区域的pH呈下降的趋势,阴极区域的pH呈上升的趋势,且反应稳定后阴极和阳极区域的pH值之和等于14;在反应器中的不同区域内,各重金属离子的去除效果均不同,阳极区域的去除效果最佳;在样品初始浓度为90g/L、pH值为6.82的条件下,当电压为40V,电解时间为4h时,对养殖粪便的处理效果与费用最佳,此时反应器中Cu2+、Zn2+、Cd2+、Pb2+等重金属离子的去除率分别为62.32% 、79.78%、55.37%、58.56%,处理1m3的养殖粪便所需的费用为10.75元。

关键词: 晚稻, 晚稻, 施氮量, 栽插密度, 穗颈瘟

Abstract: The heavy metals such as Cu2+, Zn2+, Cd2+ and Pb2+ in the livestock manure from one farm in Yong’ an Town, Liuyang City were treated with the electrochemical method of graphite as anode and stainless steel plate as cathode. The effects of electrolytic voltage and electrolytic time on pH value and heavy metals (Cu2+, Zn2+, Cd2+ and Pb2+) of livestock manure were studied. Moreover, the cost of energy consumption for removal heavy metals from livestock manure was calculated. The results showed that the pH value of manure in the anode region decreased, while it in the cathode region increased. The sum of the pH values of the cathode and the anode area was 14 under reaction stability condition. In different regions of the reactor, the removal effect of different heavy metals was different; in particular, the removal effect of heavy metals among the anode region was the best. Under the initial concentration of the sample 90 g/L, pH 6.82, voltage 40 V, and the reaction time 4 h, the removal of heavy metals from livestock manure reached the optimal balance between effect and cost. The removal percentage of Cu2+, Zn2+, Cd2+ and Pb2+ from livestock manure was 62.32%, 79.78%, 55.37%, and 58.56%, respectively. In this case, the cost of treating 1 m3 of manure was RMB 10.75.