利用热镀锌厂锌尘生产液体有机锌肥的研究

doi:10.11924/j.issn.1000-6850.casb2021-0705

中国农学通报 ›› 2022, Vol. 38 ›› Issue (15): 91-97.doi: 10.11924/j.issn.1000-6850.casb2021-0705

• 资源·环境·生态·土壤 • 上一篇下一篇

利用热镀锌厂锌尘生产液体有机锌肥的研究

马文舟¹(), 陈妍妍², 吴洪生³(), 王晓云⁴, 孙倩³, 丁军³, 李妍慧³, 刘政³, 蔡云彤⁴, 徐金益⁵, 张金福⁶, 殷文⁷, 张绪美⁸, 许建华⁹

¹盱眙县耕地质量保护站,江苏盱眙 211700
²南京市核辐照中心,南京 210012
³南京信息工程大学农业资源与环境系, 南京 210044
⁴兴化市农业技术推广中心,江苏兴化 225500
⁵无锡市农业技术推广总站,江苏无锡 214021
⁶南京市高淳区耕地质量保护站,江苏高淳 211300
⁷泰兴市农技推广中心,江苏泰兴 225400
⁸太仓市农业技术推广中心,江苏太仓 215400
⁹南京市环境监测总站,南京 210012

收稿日期:2021-07-21 修回日期:2021-11-05 出版日期:2022-05-25 发布日期:2022-06-07
通讯作者: 吴洪生
作者简介:马文舟,男,1967年出生,江苏盱眙人,高级农艺师,本科,主要从事土壤肥料技术推广。通信地址：211700 江苏省盱眙县十里营大道98号,Tel：0517-88279510,E-mail： xytfz2017@163.com。
基金资助:
国家自然科学基金项目“西瓜连作障碍土壤微生物群落结构-功能模型及土壤功能预测”(31670500);南京市环保局项目“镀锌厂锌灰综合利用生产有机锌肥”(201614);苏州市科技重点研发计划“土壤生态功能退化条件下设施蔬菜高效生态栽培关键技术研究与示范(SNG2018088)

Production of Liquid Organic Zinc Fertilizer by Reusing Zinc Ash Waste from Hot Dipped Galvanizing Plant

MA Wenzhou¹(), CHEN Yanyan², WU Hongsheng³(), WANG Xiaoyun⁴, SUN Qian³, DING Jun³, LI Yanhui³, LIU Zheng³, CAI Yuntong⁴, XU Jinyi⁵, ZHANG Jinfu⁶, YIN Wen⁷, ZHANG Xumei⁸, XU Jianhua⁹

¹Xuyi County Arable Land Quality Protection Station, Xuyi, Jiangsu 211700
²Nanjing City Nuclear Radiation Center, Nanjing 210012
³Nanjing University of Information Science and Technology, Nanjing 210044
⁴Xinghua City Agricultural Technology Extension Station, Xinghua, Jiangsu 225500
⁵Wuxi City Agricultural Technology Extension Station, Wuxi, Jiangsu 214021
⁶Nanjing City Gaochun Arable Land Quality Protection Station, Gaochun, Jiangsu 211300
⁷Taixing Agricultural Technology Extending Center, Taixing, Jiangsu 225400
⁸Taicang City Agricultural Technology Extension Station, Taicang, Jiangsu 215400
⁹Nanjing City Environmental Monitoring Station, Nanjing 210012

Received:2021-07-21 Revised:2021-11-05 Online:2022-05-25 Published:2022-06-07
Contact: WU Hongsheng

摘要/Abstract

摘要：

旨在从固废资源化利用的角度研究热镀锌厂锌尘制作农业上的微量元素肥料,变废为宝,发展循环经济。以热镀锌厂锌尘为试材,采用无机酸、无机酸-有机酸混合酸浸提锌尘中锌元素,制作液体有机锌肥,用ICP-OES测定溶液中锌的含量。结果表明,较大的称样量和较高浓度酸反应,ICP测定的结果误差较小,以称样量5~10 g比较好。用单一酸处理没有混合酸处理效果好,以无机酸与有机酸混合处理效果较好。混合酸浸提液处理花生、大豆、紫玉糯种子,低浓度(1.5 mg/L)能提高种子发芽率,高浓度(6.5 mg/L)抑制种子发芽,当达到45 mg/L时,所有作物种子不能萌发。同样低浓度锌肥促进作物幼苗生长,高浓度抑制作物幼苗生长,当锌浓度达到85 mg/L时,紫玉糯生物量比对照减少80%,但对大豆生长影响较小。利用盐酸和柠檬酸混合酸生产液体有机锌肥,既能解决热镀锌厂锌尘环境污染问题,又能解决农田土壤缺锌问题,促进作物生长。

关键词: 热镀锌, 锌尘, 有机锌肥, 液体肥料, 大豆

Abstract:

The aims are to study the production of microelement fertilizer using zinc ash waste from hot dipped galvanizing plant from the perspective of solid waste resource utilization, to change waste into valuables and to develop the recycle economy. The zinc ash waste from hot dipped galvanizing plant was used as material in this study. Inorganic acid and a mixture of inorganic acid and organic acid were used to extract zinc from zinc ash to prepare liquid organic zinc fertilizer. ICP-OES was used to determine zinc concentration of the liquid. The results showed that relatively small sample weighing error was found under large sample weighing amount and high concentration of acid, and good result was obtained when the sample weighing amount of zinc was 5-10 g. Better effect was achieved with the mixture of inorganic acid and organic acid compare to that of single acid. The best dissolving effect of zinc ash was gained by the mixture of inorganic acid and organic acid. The extract of zinc ash by mixing acids was used to treat seeds of peanut, soybean and purple maize. The germinating rate of seeds was increased at low concentration of zinc (1.5 mg/L), while high concentration of zinc (6.5 mg/L) inhibited the germinating rate and all seeds did not germinate at the concentration of 45 mg/L. The low concentration of zinc extract could promote seedlings’ growth but high concentration had an inhibition effect. When the concentration of zinc was 85 mg/L, there was a reduction of purple maize biomass of 80% compared to that of the control, but the effect on soybean growth was small. It is concluded that a mixture of inorganic acid and organic acid can be used to make liquid organic zinc fertilizer which can solve the problems of environmental pollution caused by zinc ash waste and soil zinc deficiency, and promote crop growth.

Key words: hot dipped galvanizing zinc, zinc ash, organic zinc fertilizer, liquid fertilizer, soybean

中图分类号:

S513

马文舟, 陈妍妍, 吴洪生, 王晓云, 孙倩, 丁军, 李妍慧, 刘政, 蔡云彤, 徐金益, 张金福, 殷文, 张绪美, 许建华. 利用热镀锌厂锌尘生产液体有机锌肥的研究[J]. 中国农学通报, 2022, 38(15): 91-97.

MA Wenzhou, CHEN Yanyan, WU Hongsheng, WANG Xiaoyun, SUN Qian, DING Jun, LI Yanhui, LIU Zheng, CAI Yuntong, XU Jinyi, ZHANG Jinfu, YIN Wen, ZHANG Xumei, XU Jianhua. Production of Liquid Organic Zinc Fertilizer by Reusing Zinc Ash Waste from Hot Dipped Galvanizing Plant[J]. Chinese Agricultural Science Bulletin, 2022, 38(15): 91-97.

图/表 6

参考文献 26

[1]	李荣生. 铁丝热镀锌废弃物的综合利用[J]. 轻工环保, 1994:22-23.
[2]	马东奎. 综合治理热镀锌产生的废弃物方法[J]. 黑龙江环境通报, 1992:7-11.
[3]	BARAKAT M A. The pyrometallurgical processing of galvanizing zinc ash and flue dust[J]. Journal of materials, 2003:22-29.
[4]	BAYAT B. Combined removal of zinc(II) and cadmium(II) from aqueous solutions by adsorption onto high-calcium turkish fly ash[J]. Water, air, and soil pollution, 2002, 136:69-92. doi: 10.1023/A:1015296032528 URL
[5]	XU C, HUANG Q X, ALHADJ-MALLAH M M, et al. Characterization of zinc vapor condensation in fly ash particles using synchrotron X-ray absorption spectroscopy[J]. Zhejiang university-science a (application physics & engineering), 2015, 16(1):70-80.
[6]	马东奎. 利用热镀锌产生的锌灰-生产硫酸锌[J]. 江苏环境科技, 1994:42-43.
[7]	DVORAK P, JANDOVA J. Hydrometallurgical recovery of zinc from hot dip galvanizing ash[J]. Hydrometallurgy, 2005, 77:29-33. doi: 10.1016/j.hydromet.2004.10.007 URL
[8]	SHAH F, HUSSAIN S, KHAN F, et al. Effects of tire rubber ash and zinc sulfate on crop productivity and cadmium accumulation in five rice cultivars under field conditions[J]. Environmental science pollution research, 2015, 22:12424-12434. doi: 10.1007/s11356-015-4518-3 URL
[9]	KIRBY J, MAHER W, HARASTI D. Changes in selenium, copper, cadmium, and zinc concentrations in mullet (Mugil cephalus) from the southern basin of lake macquarie, australia, in response to alteration of coal-fired power station fly ash handling procedures[J]. Toxicology, 2001, 41:171-181.
[10]	MARIA M, BEATRICE M, TADDEI M, et al. Environmental sustainability assessment of the management of municipal solid waste incineration residues: a review of the current situation[J]. Clean technology environmental policy, 2015, 17:1333-1353. doi: 10.1007/s10098-015-0961-6 URL
[11]	VISHAL M. Biosorption of zinc ion: a deep comprehension[J]. Application water sciencem, 2014, 4:311-332.
[12]	BRAM V, BILLEN P, CANEGHEM J V, et al. Recycling of mswi bottom ash: a review of chemical barriers[J]. Engineering applications and treatment technologies, 2016,DOI 10.1007/s12649-016-9704-0.
[13]	陈金. 热镀锌锌灰、锌渣的再生利用研究[D]. 唐山: 河北理工大学, 2007:6-11.
[14]	何小风, 李运刚, 陈金. 热镀锌渣锌灰回收处理工艺评述[J]. 中国有色冶金, 2008:55-58.
[15]	RAMÍREZ‑OJEDA A M, MORENO‑ROJAS R, SEVILLANO‑ MORALES J, et al. Influence of dietary components on minerals and trace elements bioaccessible fraction in organic weaning food: a probabilistic assessment[J]. European food research technology, 2016, DOI 10. 1007/s00217-016-2777-y.
[16]	ANNALISA Z, BORGESE L, GIANONCELLI A, et al. Review of fly ash inertisation treatments and recycling[J]. Environmental chemistry Letter, 2014, 12:153-175.
[17]	李德超, 翁林山, 刘江平. 热镀锌锌灰缺陷形成分析及改进研究[J]. 轻工环保, 2010:5-7.
[18]	曹恭, 梁鸣早. 锌-平衡栽培体系中植物必需的微量元素[J]. 土壤肥料, 2003(6):2-3.
[19]	谢潜渊, 朱巧珍. 扬州地区土壤有效锌及锌肥肥效的研究[J]. 江苏农学院学报, 1983, 4(4):27-32.
[20]	刘学剑. 微量元素锌的生物学功能及其研究进展[J]. 饲料工业, 1995, 16(8):26-29.
[21]	王志武, 孙建钢, 孙锐锋,等. 微量元素锌的生物学功能及其应用进展[J]. 饲料研究, 2005, 8:12-15.
[22]	MOUSAVI, SAYED, ROHOLLA. Zinc in crop production and interaction with phosphorus[J]. Australian journal of basic & applied sciences, 2011, 5(9):1503-1509.
[23]	吴士杰, 李庆生, 王桂维,等. 用镀锌废料锌灰制备锌肥[J]. 松辽学刊:自然科学版, 1985, 4:42-43.
[24]	孙会栋, 谢巧玲, 杨贵亭,等. 用镀管厂的废料锌灰生产七水硫酸锌的研究[J]. 化学世界, 2002, 8:446-448.
[25]	李道荣, 段素华. 人体中锌的生物学功能[J]. 生命的化学:中国生物化学会通讯, 1997, 17(1):29-31.
[26]	周毅峰, 吴永尧, 唐巧玉,等. 锌的生物学功能[J]. 氨基酸和生物资源, 2004, 26(2):11-15.

利用热镀锌厂锌尘生产液体有机锌肥的研究

Production of Liquid Organic Zinc Fertilizer by Reusing Zinc Ash Waste from Hot Dipped Galvanizing Plant

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盐酸浓度及称样量	锌尘中酸溶解出的金属
盐酸浓度及称样量	Zn	Fe	Mn	Cu	Cd	Cr	Sn	Ni	Pb
0.5 mol/L HCl (0.1 g)	4102.54	0.00	0.00	0.00	0.00	0.00	0.00	0.00	0.00
1 mol/L HCl (1 g)	285.65	9.86	7.04	0.09	0.00	0.00	0.00	0.00	0.00
0.1 mol/L HCl (5 g)	143.36	0.00	0.55	0.00	0.00	0.00	0.00	0.00	0.00
0.5 mol/L HCl (5 g)	93.24	2.07	1.56	0.02	0.00	0.00	0.00	0.00	0.00
1 mol/L HCl (10 g)	86.53	0.96	0.00	0.01	0.00	0.00	0.00	0.00	0.00

硫酸浓度和称样量	锌尘中酸溶解出的金属
硫酸浓度和称样量	Zn	Fe	Mn	Cu	Cd	Cr	Sn	Ni	Pb
0.1 mol/L H₂SO₄ (1 g)	179.23	3.61	0.00	0.02	0.00	0.00	0.00	0.00	0.00
0.5 mol/L H₂SO₄ (1 g)	216.49	11.17	0.00	0.09	0.00	0.00	0.00	0.00	0.00
1 mol/L H₂SO₄ (0.1 g)	83.46	0.00	0.00	0.00	0.00	0.00	0.00	0.00	0.00
1 mol/L H₂SO₄ (1 g)	85.32	10.58	6.95	0.11	0.00	0.00	0.00	0.00	0.00
1 mol/L H₂SO₄ (5 g)	89.46	6.76	0.00	0.04	0.00	0.00	0.00	0.04	0.00

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