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中国农学通报 ›› 2014, Vol. 30 ›› Issue (21): 52-58.doi: 10.11924/j.issn.1000-6850.2013-2824

所属专题: 小麦

• 农学 农业基础科学 • 上一篇    下一篇

30%苯醚甲环唑?丙环唑EC在小麦上的残留研究

王梅 陈雨   

  • 收稿日期:2013-10-30 修回日期:2014-05-13 出版日期:2014-07-25 发布日期:2014-07-25
  • 基金资助:
    公益性行业 (农业) 专项——农药高效安全施用技术(200903033)。

Study on the Residue of 30% Difenoconazole·Propiconazole EC on Wheat

  • Received:2013-10-30 Revised:2014-05-13 Online:2014-07-25 Published:2014-07-25

摘要: 30%苯醚甲环唑·丙环唑EC是中国防治小麦纹枯病的主要杀菌剂之一。为明确30%苯醚甲环唑·丙环唑EC在小麦籽粒、植株及土壤中的残留与消解动态,分别于2011和2012年在小麦田进行小麦纹枯病防治试验,并在施药后不同时期采集小麦籽粒、植株与土壤样本,通过气谱(配ECD检测器)进行相关样本的药剂残留检测。检测结果表明,2011年,苯醚甲环唑在土壤和小麦植株上的原始沉积量分别为0.1033 mg/kg和4.0498 mg/kg,半衰期(T1/2)分别为15.5天和8.6天,丙环唑在土壤和小麦植株上的原始沉积量分别为0.0940 mg/kg和2.0329 mg/kg,T1/2分别为23.9天和6.8天;2012年,苯醚甲环唑在土壤和小麦植株上的原始沉积量分别为0.0910 g/kg和4.0498 mg/kg,T1/2分别为13.0天和8.6天,丙环唑在土壤和小麦植株上的原始沉积量分别为0.0723 mg/kg和2.3507 mg/kg,T1/2分别为22.1天和6.5天。最终残留试验表明:苯醚甲环唑在小麦植株、小麦籽粒和土壤中的最终残留量分别为0.0730~2.0880 mg/kg、<0.01~0.0363 mg/kg和<0.01~0.3649 mg/kg;丙环唑在小麦植株、小麦籽粒和土壤中的最终残留量分别为0.0461~1.6396 mg/kg、<0.005~0.0307 mg/kg和<0.005~0.1036 mg/kg。由此得出,30%苯醚甲环唑·丙环唑EC可以在小麦上使用,但施药剂量最高为135 a.i.g/hm2,施药3~4次,安全间隔期为35天。

关键词: 合作, 合作

Abstract: 30% difenoconazole·propiconazole EC is one of the important fungicides for the control of sharp eye spot of wheat in China. In order to determine the residue and the degradation of 30% difenoconazole·propiconazole EC in wheat seeds, wheat plants and soil, field trials were conducted and the related samples were collected after the fungicide spraying and the residues of difenoconazole and propiconazole was detected through GC-ECD. The detection results showed that in 2011, the residues of difenoconazole in soil and wheat plants were 0.1033 mg/kg and 4.0498 mg/kg, with the half life (T1/2) of 15.5 days and 8.6 days, respectively; the residues of propiconazole in soil and wheat plants were 0.0940 mg/kg and 2.0329 mg/kg, with the half life of 23.9 days and 6.8 days, respectively. And in 2012, the residues of difenoconazole in soil and wheat plants were 0.0910 g/kg and 4.0498 mg/kg, with the half life of 13.0 days and 8.6 days, respectively; the residues of propiconazole in the soil and wheat plants were 0.0723 mg/kg and 2.3507 mg/kg, with the half life of 22.1 days and 6.5 days, respectively. The results of the final residue experiments showed that the final residues of difenoconazole in wheat plants, wheat seeds and soil were 0.0730-2.0880 mg/kg,<0.01-0.0363 mg/kg and<0.01-0.3649 mg/kg, respectively, and the final residues of propiconazole in wheat plants, wheat seeds and soil were 0.0461- 1.6396 mg/kg,<0.005- 0.0307 mg/kg and<0.005- 0.1036 mg/kg, respectively. The 30% difenoconazole·propiconazole EC can be applied to wheat 3 to 4 times with the maxmium dosage of 135 a.i. g/ hm2 and 35 days of recovery interval.